Page 166 - [B._MURPHY,_C._MURPHY,_B._HATHAWAY]_A_working_meth

150 Subject Index
Cell(s) (cont.) Electrolysis
potential, 76-78 aqueous concentrated hydrochloric
Celsius, 9 acid, 101-102
Charles’s law, 5-6 aqueous concentrated sodium
Chemical chloride, 98-101
equilibrium, 36-62 aqueous sulfuric acid, 102-103
kinetics, 1 13-146 molten sodium choride, 97-98
thermodynamics, 24-35 Faraday’s laws, 90-9 1
Chlorate oxyanion, 4 Electrolyte, 89
Chloric acid, 4 Electrolytic cells, 92-93
Coefficients of gaseous reagents, 7, Electromotive force (EMF), 71
25,39 Elementary reaction, 128
Combustion, 22-23 Endothermic process, 26
Common ion effect, 48-50 End-point, 51
Concentrated acids and bases, 2 Energy
Conjugate acids and bases, 3 activation, 129-1 30
Conservation of energy, 63-64 forms, 63
Constant( s) Gibbs free, 31
acid, 47 heat, 63
base, 47-48 internal, 18
equilibrium, 35 kinetic, 63, 129
hydrolysis, 52-53 light, 63
specific rate, 1 14 nuclear, 63
universal gas, 7 potential, 63
water, 50 sound, 63
Coulomb, 76 Enthalpy, 18-20
of formation, molar, 20
Daniel cell, 72 Entropy, 2,29-31
Density, 10 Equations
Dilute acids and bases, 2 balancing redox, 65-67
Diprotic acids, 2 quadratic, 41
Down-hill process, 64 Equilibrium, 36-62
Downs cell, 97-98 Ethanoate oxyanion, 48
Ethanoic acid, 48
Electrochemical series, 74-75,9695 Exothermic process, 26
Electrochemistry, 65 Expansion work, 18-19
Electrode
definition, 68 Faraday constant, 76
gas-ion, 69-70 Faraday’s laws of electrolysis,
metal-insoluble salt anion, 70-71 90-9 1
metal in two different valence Free energy, 31
states, 69
metal-metal-ion, 68-69 Galvanic cells, 63-88
potential, 71 Gas(es)
standard hydrogen (SHE), 70 ideal, 6,8