Page 168 - [B._MURPHY,_C._MURPHY,_B._HATHAWAY]_A_working_meth
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152 Subject Index
Partial pressure, 3840 definition, 3, 51
equilibrium constant, 39 Second-order reactions, 1 17-1 18
Pascal, 4 half-life, 120
Perchlorate oxyanion, 4 SI units, 9-10
Perchloric acid, 4 Slow-s tep, see Ra te-de termining
PH, 11 step
definition, 50 Solid(s), properties, 2
relation to pOH, 50 Solubilities, molar, 59-60
scale, 51 Solubility product, 59-60
Phase, aqueous, 2 Solution, equilibria, aqueous, 47-62
Phenolphthalein, 5 1-52 Spectator ion, 57
Phosphate oxyanion, 4 Spontaneous change, 3 1
Phosphite oxyanion, 4 Standard
Phosphoric acid, 4 hydrogen electrode (SHE), 72
Phosphorous acid, 4 reduction potentials, 71
POH state, 9, 19, 71
defintion, 50 State(s)
relation to pH, 50 function, 20-21
Polar molecules, 9 matter, 2
Polyprotic acids, 59 non-standard, 9
Potential@) standard, 9, 19,71
cell, 71 Stoichiometry factors, 33,41, 122
energy, 63 Sulfate oxyanion, 4
Precipitation, 84 Sulfite oxyanion, 4
Pressure(s) Sulfuric acid, 4
partial, 38-40 Sulfurous acid, 4
units of, 4 Surroundings, 17
Proportionality, 90 System, 17
Proton, 2,4748, 59
Temperature(s), 9
Rate Termolecular reaction, 128
constant, 114 Thermodynamic(s), 24-35
-determining step, 126-1 27 Third law of thermodynamics, 30-3 1
law, 114 Titration curves, 51-52
reaction, 11 3-1 14
Real gas, 6,8 Unimolecular reaction, 128
Redox reactions, 65-67 Units, 9-10
Reducing agent, 66 derived, 10
Reduction non-SI, 10
definition, 74 Universe, 17
potentials, 71, 74 Up-hill process, 64
Salt(s) Van der Waals forces, 9
bridge, 73 Volume, molar, 7
