Page 422 - Adsorbents fundamentals and applications

SUBJECT INDEX 407

Fredholm integral equation, 75 Magnetic field, effect on adsorption, 302
Monte Carlo techniques, 76 Magnetic susceptibility, 10, 185
Interaction potential or energy, 8–12, Mass separation agent, 1
57–65, MCM-41, 131, 133
of molecules on zeolites, 185 applications of MCM as sorbents, 140
International zeolite association (IZA), 164 as sorbent for VOC, 140
Ion exchange by resins, 269 formation of MCM-type materials,
Ion exchange on activated carbon, 102 139
Ion-exchanged resins, 192, 201, 202 functionalization of, 140
as π-complexation sorbents, 192, 201, silanol numbers on MCM, 136
202 MCM-48, 136, 143–145
Ionic radius, 14, amine-grafted MCM-48, 143–145
of cations in zeolites, 175 Meissner effect, 302
effects of ionic radius on adsorption, 183 Metal hydrides, 306–308
Isomorphous substitution, 157 ball-milling, 308
IsoSiv process, 161 intermetallic compounds, 307
nanocrystalline, 308
Jaroniec-Choma isotherm for PSD, 75 sodium alanates, 308
Jet fuel desulfurization (see desulfurization of Methane storage, 321–326
transportation fuels) as liquefied natural gas, 321
DOE target for, 322
Keggin structure, 259, 365, 366 effects of chemical modification of carbons,
Kelvin equation, 54 325
for pore size distribution, 54, 76 in various sorbents, 323
Kinetic diameters of molecules, 162 micropore volume for, 322
Kinetic separation, 2, 3, 18 on super-activated carbon, 324, 325
of N 2 /CH 4 , 334–344 on zeolites, 325
Kirkwood-Muller formula, 10, 56, 58, 185 packing density for, 322, 323
theoretical limit of activated carbon for, 322
Langmuir–Freundlich isotherm, 19 Mn-based oxides for NO x removal, 367–371
Langmuir isotherm, 18 Molecular imprinting with silicas, 141, 144,
extended Langmuir isotherms for mixtures, 147
18 Molecular orbital theory, 202
Laser vaporization for growing carbon ab initio methods, 204
nanotubes, 241–243 all-electron basis set, 206
catalysts in, 242, 243 basis set, 205
Layered beds, 304 calculation of adsorption bond energy by,
adsorption in, 304, 305 207, 213
Length of unused bed, 17 calculations of H on carbon nanotubes,
Lennard-Jones potential, 10, 56, 57, 185 316
Li-LSX, 180 density functional theory (DFT), 203
cation sites, 285 double-zeta basis set, 206
for air separation, 180–182, 281, 283–295 effective core potentials (ECP), 205
mixed NaLi-LSX, 286 MINDO, 203
O 2 and N 2 isotherms, 285, 285 MOPAC, 203
PSA/VSA air separation with, 295 model chemistry, 206
Loading ratio correlation, 20 molecular systems, 206
Low-silica type X zeolite (LSX), 180 natural atomic orbital (NAO), 209
Ag-LSX, 181 Schr¨ odinger equation, 202
air separation by Ag-LSX, 181 semi-empirical methods, 203
N 2 /O 2 adsorption on Li/Na-LSX zeolite, 181 Slater-type orbital (STO), 205
synthesis of, 284 split valence basis set, 205
Low-volatile compounds, isotherm Molecular sieves, 157
measurements of, 244 Møller-Plesset (MP) perturbation theory, 204