Page 423 - Adsorbents fundamentals and applications

408 SUBJECT INDEX

Monolayer dispersion, 193 Olefin-Ag bond, 109–211
monolayer capacities of salts on alumina, 197 d-π* backdonation, 210–212
of CuCl, 194, 196 σ-donation, 210–212
of CuCl double salts, 195 Organosilanes, 142
of water-insoluble salts, 194 Oxygen product cost by PSA/VSA, 281
supported monolayer salts, 193 Oxygenates removal, 151
Monte Carlo simulations, of adsorption on
carbon nanotubes, 248, 252 Permanent dipole moment, 10
of CH 4 storage in activated carbon, 322 effect on adsorption, 11
of H 2 storage in carbon nanotubes, 316 π-complexation sorbents, 191, 192
MOPAC method, 203 Ag-exchanged zeolites as, 198
Mordenite, 163, 167 between sorbate and sorbent, 191
Mullekin population analysis, 207 by reduction of supported CuCl 2 , 196, 197
calculation of bond energy, 208
N 2 /CH 4 separation, 334–344 comparison of Cu and Ag , 212
+
+
by 4A zeolite, 336 CuCl/NaY, 218
by carbon molecular sieves, 336 Cu-exchanged zeolites as, 199
by clinoptilolite, 336–341 d-orbital electrons for, 192, 212
by various sorbents, 344, 345 d-π* backdonation, 210–212, 215
kinetic separation of, 334–344 effects of anions and substrates on, 213–215
PSA simulation for, 344 for CO separation, 196
Natural bond orbital (NBO), 207 for desulfurization of transportation fuels,
Natural gas upgrading (see N 2 /CH 4 separation) 350–361
Nonspecific interactions, 9 for olefin/paraffin separations, 326–334
NO x removal, 363–371 ion-exchanged zeolites as, 192, 197
by activated carbon fibers, 363 molecular orbital theory for, 192
by CuO based sorbents, 371 nature of π-complexation by molecular
by Fe-Mn oxides, 367, 369 orbital theory, 208
by heteropoly compounds, 364–366 preparation/synthesis of, 192
by Mn based oxides, 367–371 reversibility of, 191, 192
by superconducting oxides, 370 σ-donation, 210–212, 215
from combustion gases, 363–371 understanding of π-complexation by MO
high temperature sorbents for, 370–171 theory, 209
selective adsorption for, 363–371 useful bond energies for, 192
Pillared clays (PILC), 253–264
O 2 and N 2 isotherms: adsorption of CO 2 , 261
on 5A and 13X, 282–284 adsorption of N 2 /O 2 , 261
on AgLi-LSX, 294 adsorption of water, 261
on Ag-LSX, 293 adsorption properties of, 260
on CaA, 283 ammonia treatment of, 260
on Li-LSX, 285 as supports, 262
on MgA, 283 CuCl supported on PILC, 263
O 2 selective sorbents, 296 ion-exchange of PILCs, 260
cobalt complexes as, 296–303 micropore size distribution of, 256–259
Olefin/paraffin separations, 219, 326–334 pore sizes, 253
by PSA, 326–334 syntheses of, 253
multiple steady states in PSA for, 333 XRD of, 257
on Olesorb-1, 334 Point of zero charge, 101
with AgNO 3 /clays, 334 Polarizability, 10, 12, 13, 185
with AgNO 3 /SiO 2 , 327–334 effect on adsorption, 11, 184, 185
with AlPO 4 -14, 327–334 Polymeric adsorbents, 267
with CuCl/α-Al 2 O 3 , 327, 328 Polymeric resins, 264–273
with π-complexation sorbents, adsorption of VOCs, 268
327–334 adsorption of water on, 268