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234    CHAPTER 10 THERMODYNAMICS OF COMBUSTION




              P10.6 A gas injection system supplies a mixture of propane (C 3 H 8 ) and air to a spark-ignition
                     engine, in the ratio of volumes of 1:30. The mixture is trapped at 1 bar and 300 K, the
                     volumetric compression ratio is 12:1, and the index of compression, k ¼ 1.4. Calculate the
                     equivalence ratio, the maximum pressure and temperature achieved during the cycle, and
                     also the composition (by volume) of the dry exhaust gas.
                     [0.79334, 119.1 bar, 2883 K; 0.8463, 0.1071, 0.0465]
              P10.7 A turbocharged, intercooled compression ignition engine is operated on octane (C 8 H 18 ) and
                     achieves constant pressure combustion. The volumetric compression ratio of the engine is 20:
                     1, and the pressure and temperature at the start of compression are 1.5 bar and 350 K,
                     respectively. If the air-fuel ratio is 24:1 calculate maximum temperature and pressure
                     achieved in the cycle, and the indicated mean effective pressure (imep, p ) of the cycle in
                                                                                i
                     bar. Assume that the index of compression, k c ¼ 1:4, while that of expansion, k e ¼ 1:35.
                     [2495 K; 99.4 bar; 20.57 bar]
              P10.8 One method of reducing the maximum temperature in an engine is to run with a rich mixture.
                     A spark-ignition engine with a compression ratio of 10:1, operating on the Otto cycle, runs on
                     a rich mixture of octane (C 8 H 18 ) and air, with an equivalence ratio of 1.2. The trapped
                     conditions are 1 bar and 300 K, and the index of compression is 1.4. Calculate how much
                     lower the maximum temperature is under this condition than when the engine was operated
                     stoichiometrically. What are the major disadvantages of operating in this mode?
                     [208 C]

              P10.9 A gas engine with a volumetric compression ratio of 10:1 is run on a weak mixture of methane
                     (CH 4 ) and air, with an equivalence ratio, f ¼ 0.9. If the initial temperature and pressure at the

                     commencement of compression are 60 C and 1 bar respectively, calculate the maximum
                     temperature and pressure reached during combustion at constant volume if compression is
                     isentropic, and 10% of the heat released during the combustion period is lost by heat transfer.
                       Assume the ratio of specific heats, k, during the compression stroke is 1.4, and the heat of
                                                                          5
                     reaction at constant volume for methane at 25 Cis  8.023   10 kJ/kmol CH 4
                     [2817 K; 84.59 bar].
             P10.10 A jet engine burns a weak mixture (f ¼ 0.32) of octane (C 8 H 18 ) and air. The air enters the
                     combustion chamber from the compressor at 10 bar and 500 K; assess if the temperature of
                     the exhaust gas entering the turbine is below the limit of 1300 K. Assume that the
                     combustion process is adiabatic and that dissociation can be neglected. The enthalpy of
                     reaction of octane at 25 Cis  44,880 kJ/kg, and the enthalpy of the fuel in the reactants

                     may be assumed to be negligible.
                     [Maximum temperature, T P ¼ 1298 K; value is very close to limit]
             P10.11 A gas engine is run on a chemically correct mixture of methane (CH 4 ) and air. The
                     compression ratio of the engine is 10:1, and the trapped temperature and pressure at inlet
                     valve closure are 60 C and 1 bar, respectively. Calculate the maximum temperature and

                     pressure achieved during the cycle if:
                       (a)combustion occurs at constant volume;
                       (b)10% of the energy added by the fuel is lost through heat transfer;
                       (c)the compression process is isentropic.
                       It can be assumed that the ratio of specific heats, k ¼ 1.4, and that the internal energy of
                     methane in the reactants is negligible.
                     [2956 K; 88.77 bar]
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