Page 279 - Advances in Forensic Applications of Mass Spectrometry - Jehuda Yinon

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APCI
Abundance 295
-
[M-1]
55000
50000 102
45000
40000
35000
30000
25000
342
20000
129 203 398
15000
10000 147
5000 174 322
81 224 251 285 373 425 499
0
m/z->
100 150 200 250 300 350 400 450
Electrospray
Abundance 409
-
[M+TFA]
65000
60000
55000
50000 -
[M+Cl]
45000
40000
331
35000
30000
25000
20000
113
15000
10000
5000 147 295 358
82 100 174 216231 253 385 427 451 483 511 535
0
m/z->
100 150 200 250 300 350 400 450 500
Figure 6.13 APCI and ESI mass spectra of HMX. (From Schilling, A.B., The
analysis of explosives constituents and metabolites with electrospray and APCI
LC/MS, presented at 44th ASMS Conference on Mass Spectrometry and Allied
Topics, Portland, OR, 1996.)
NO NO 2
N N
CH 2 CH 2 CH 2 CH 2

N N N N
O N CH 2 NO O N CH 2 NO
2
2
DNX MNX
Scheme 6

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