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                    Gas-Phase Biofiltration                                                   425

                    Table 2
                    Disadvantages of Conventional Biological Odor Abatement Technologies
                         Conventional                Conventional               Conventional
                          biofilters              tricklebed biofilters         bioscrubbers
                    • Packing is usually non-  • Biological overgrowth    • More energy intensive
                       homogeneous, often       leading to increased ∆p  .   than conventional
                                                                   bed
                       preventing a uniform   • Low specific area to         packed-bed biofiltration.
                       gas distribution →       reduce ∆p  .              • Because of the large
                                                         bed
                       shortcircuiting.       • Drain water has to be        amount of liquid, there
                    • Low specific gas flow     continuously separated       is a danger of active
                       (average for compost     from excess biomass          microorganisms being
                                3
                       beds 150 m gas/h/m 2     before being recycled.       carried away.
                       bed, max. up to 500 m 3  • Fresh water must be     • More sensitive than
                             2
                       gas/h/m bed).            constantly fed to the        packed-bed biofilters to
                    • Aging phenomenon,         system because of losses.    feed fluctuations.
                       resulting in:          • Nonhomogeneous            • Operation takes place in
                       • Lumping.               temperature and              more than one unit. The
                       • Drying out             concentration profiles.      sludge tank often
                       • Developing of                                       requires extra stirring
                         anaerobic zones                                     and oxygenation.
                         because of moisture                              • Periodic removal of
                         accumulation.                                       sludge.
                       • Development of
                         shrink cracks
                       • Bed compaction
                       • Difficulty in
                         maintaining an
                         even bed pH




                    address these limitations, so that biofilters may be used in a wider range of applications.
                    If gas-phase biofiltration is going to receive increased takeup industrially, it is vital that
                    the stability, efficiency, and range of operating conditions are improved. This section
                    briefly addresses a number of the potential emerging technologies.
                    2.2.1. Pollutant Solubility in the Aqueous Phase
                       As described earlier, pollutant solubility may be an issue dictating method choice.
                    Some researchers have attempted to address the limitations of water solubility by using
                    surfactants in the biofiltration beds (7,8). The theory is that the increased solubility of
                    the chemicals in the bed will increase partitioning into the liquid phase and thus make the
                    chemicals more bioavailable. Lab studies have met with some success in applications
                    dealing with chemicals produced by the forest products industry. In addition to attempts
                    to increase solubility, changing the airflow rate has also been attempted. Because the
                    process generally sets the airflow rates, the changes have to be made prior to the biofil-
                    tration system. These changes in flow rate are accomplished via adsorption/desorption
                    systems; that is, high-flow, low concentrations are adsorbed on to a suitable substrate
                    (i.e., activated carbon) and are then desorbed at a lower flow rate and possibly higher
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