Page 13 - Air pollution and greenhouse gases from basic concepts to engineering applications for air emission control
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xii                                                         Contents

                9.5   In-combustion Soot Control . . . . . . . . . . . . . . . . . . . . . . . .  272
                9.6   Engine Exhaust Gas Recirculation. . . . . . . . . . . . . . . . . . . .  273
                9.7   Practice Problems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  274
                References and Further Readings . . . . . . . . . . . . . . . . . . . . . . . . . .  275

            10 Post-combustion Air Emission Control. ... .. ... .. ... .. ... ..  277
                10.1  Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  277
                10.2  Control of Particulate Matter Emissions . . . . . . . . . . . . . . . .  277
                      10.2.1  Electrostatic Precipitator Designs . . . . . . . . . . . . . .  278
                      10.2.2  Filtration System Designs . . . . . . . . . . . . . . . . . . .  280
                      10.2.3  Wet Scrubbing. . . . . . . . . . . . . . . . . . . . . . . . . . .  285
                10.3  Flue Gas Desulfurization . . . . . . . . . . . . . . . . . . . . . . . . . .  288
                      10.3.1  Wet FGD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  288
                      10.3.2  Steam Reactivation of Calcium Based Sorbents . . . .  291
                      10.3.3  Dry FGD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  294
                      10.3.4  Semi-Dry FGD . . . . . . . . . . . . . . . . . . . . . . . . . .  294
                10.4  NO x Reduction Using SCR and SNCR . . . . . . . . . . . . . . . .  295
                      10.4.1  Selective Catalytic Reduction . . . . . . . . . . . . . . . .  295
                      10.4.2  SNCR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  296
                      10.4.3  Reagents. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  297
                10.5  Simultaneous Removal of SO x and NO x . ... .. ... .. ... ..  297
                10.6  Control of Volatile Organic Compounds . . . . . . . . . . . . . . .  298
                      10.6.1  Volatile Organic Compounds Adsorption . . . . . . . .  299
                      10.6.2  Oxidation of VOCs . . . . . . . . . . . . . . . . . . . . . . .  299
                      10.6.3  Flaring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  300
                      10.6.4  Thermal Oxidizers . . . . . . . . . . . . . . . . . . . . . . . .  300
                      10.6.5  Catalytic Oxidation . . . . . . . . . . . . . . . . . . . . . . .  303
                      10.6.6  Other Approaches to Volatile Organic
                              Compounds Control . . . . . . . . . . . . . . . . . . . . . . .  304
                10.7  Control of Soot Particles . . . . . . . . . . . . . . . . . . . . . . . . . .  305
                10.8  Control of Trace Metals. . . . . . . . . . . . . . . . . . . . . . . . . . .  305
                      10.8.1  Mercury in Particulate Control and FGD Devices. . .  306
                      10.8.2  Mercury Adsorption by Activated Carbon . . . . . . . .  307
                      10.8.3  Mercury Captured by Metal Oxides, Silicates,
                              and Fly Ashes ... .. .. ... .. ... .. ... .. ... ..  308
                10.9  Proper Layout for Post-combustion Air Pollution Control
                      Devices . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  308
                10.10  Practice Problems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  309
                References and Further Readings . . . . . . . . . . . . . . . . . . . . . . . . . .  311

            11 Air Dispersion . ... .. ... .. ... .. .. ... .. ... .. ... .. ... ..  315
                11.1  Box Model. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .  315
                11.2  General Gaussian Dispersion Model . . . . . . . . . . . . . . . . . .  318
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