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112                                        4 Properties of Aerosol Particles

                 99.99
                 99.95
                  99.9
                  99.8
                   99                                           Number
              Cumulative % Less Than Indicated Size  50  80       Mass
                   98
                   95
                                                                distribution line
                   90

                   70
                   60
                   40
               34
                                                                  distribution line
                   30
                   20
                   10
                    5
                    2
                    1
                   0.5
                   0.2
                   0.1
                   0.0
                  0.01
                       0           1            10           100
                           Count median    Standard deviation  Mass median
                                                              diameter
                           diameter
                                   Particle Diameter (µm)
            Fig. 4.5 Cumulative lognormal distributions for the same aerosol sample

            volume, respectively. We can see that both surface and volume also follow log-
            normal distributions with the same standard deviation but with different median
            diameters. They are related to the number geometric mean diameter as follows.

                                                        2
                                 logd pgA ¼ logd pg þ 2 logrð  Þ         ð4:56Þ
                                                        2
                                 logd pgV ¼ logd pg þ 3 logrð  Þ         ð4:57Þ
            where d pgA and d pgV are the geometric surface and volume median diameters.
            Respectively.
              A log-probabiltiy paper based on Eq. (4.55) has been widely used to aerosol
            particle size distribution analysis. If we plot the number, surface, and volume
            cumulative distributions in the same log probability paper, they are parallel straight
            lines, as seen in Fig. 4.5. We can determine the median size of particles (based on
            number or mass) and the geometric standard deviation using a chart like this.
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