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228  Analytical methods for food additives


              Table 25.3  Performance characteristics for aluminium in milk powder 1
              Sample                                Milk powder
              Analyte                                Aluminium
              No. of laboratories                       16
              Units                                    mg/kg
              Mean value                               15.87
              S                                         0.83
               r
              RSD                                      5.2 %
                  r
              r                                         2.33
              S                                         2.90
               R
              RSD                                      18.3 %
                  R
              R                                         8.21
              Key
              Mean  The observed mean. The mean obtained from the collaborative trial data.
              r     Repeatability (within laboratory variation). The value below which the absolute difference
                    between two single test results obtained with the same method on identical test material under
                    the same conditions may be expected to lie with 95 % probability.
              S     The standard deviation of the repeatability.
               r
              RSD   The relative standard deviation of the repeatability (S  × 100/mean).
                 r                                    r
              R     Reproducibility (between-lab variation). The value below which the absolute difference
                    between two single test results obtained with the same method on the identical test material
                    under different conditions may be expected to lie with 95 % probability.
              S     The standard deviation of the reproducibility.
               R
              RSD   The relative standard deviation of the reproducibility (S  × 100/mean).
                 R                                     R
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