Page 341 - Arrow Pushing in Inorganic Chemistry A Logical Approach to the Chemistry of the Main Group Elements

Index

-nomenclature Appel reaction, 187–8, 191
3
-iodanes Arbuzov reaction, 175–6
5
-iodanes Arndt–Eistert synthesis, 148
3
-bromanes aromatics, substitution on, 23–4
3
aryl- -bromanes addition–elimination, 23–4
acyloin condensation, 55 arrow pushing, 38–40
aldol reaction, 28, 69, 113 inorganic arrow pushing, 38–40
alkali and alkaline earth metals, 50–65 organic paradigms, 38
dissolving metal reactions, 56–58 arsenic toxicity, 168–71
I
I
Mg –Mg bond, 63–4 arsenic-based DNA, 166–8
3
organolithium and organomagnesium compounds, aryl- -bromanes, 294–8
58–61 trifluoromethanesulfonamide, 296
as reducing agents, 52–3 associative processes, 16–19
reductive couplings, 53–6 astatine, 257
solubility, 51–2 atom economy, 177–8
alkali-induced disproportionation of phosphorus, atomic radii, 6, 7
171–3 ATP, 50, 163–5, 168, 200
alkene analogs, 115–20 azide anion, 135–6
alkyne analogs, 120–121 azo compounds, 140–143
allylsilanes, 106–9 azobisisobutyronitrile (AIBN), 140–141
allylstannanes, 113
ammonia, 130–131 Balz–Schiemann reaction, 140
ammonium nitrate (NH 4 NO 3 ), thermal basicity, 5
decomposition, 137–8 Brønsted basicity, 6
ammonium nitrite (NH 4 NO 2 ), thermal betaine, 177
decomposition, 137–8 bimolecular -elimination (E2), 14–15
aniline yellow, 140 biological signaling, 154, 203
aniline, 138 biomethylation, 168–71
anti addition, 23 Birch reduction, 57–8

Arrow Pushing in Inorganic Chemistry: A Logical Approach to the Chemistry of the Main-Group Elements,
First Edition. Abhik Ghosh and Steffen Berg.
© 2014 John Wiley & Sons, Inc. Published 2014 by John Wiley & Sons, Inc.

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