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260    Cha pte r  Ei g h t


                                          Biodiesel (100% FAME)
                Properties            Putranjiva  Karanja  Jatropha  Diesel
                Viscosity in cSt (at 40°C)  5.81  5.81   5.42     5.03
                Cetane number         40.2      35.6     41.0     46.3
                Calorific value (kJ/kg)  3,9254  38,119  39,065   42,707
                Pour point (°C)       2         5        2        –12
                Specific gravity (at 25°C)  0.883  0.899  0.878   0.834
                Flash point (°C)      152       190      171      78
                Fire point (°C)       155       192      175      85
                Carbon residue (%)    0.10      1.20     0.15     0.10

               TABLE 8.1  Fuel Properties of Three Biodiesels and Diesel Fuel


               When we compare the three oils, Jatropha shows better results in
               specific gravity, viscosity, CN, and pour point, whereas putranjiva is
               found to be better in calorific value, flash point, and carbon residue.

               8.1.4  Measurement of Performance and Emission
               To measure emissions, an automotive exhaust analyzer and a smoke
               meter are generally used. Automotive exhaust analyzer functions
               on the principle of the nondispersive infrared (NDIR) method. The
               operational principle of the smoke meter analyzer is attenuation of
               a LED pure green light beam. The Ricardo variable compression die-
               sel engine is used to run with blends of (10, 30, 50, 70, and 100 per-
               cent) transesterified oils, with diesel at different loads (0 to 2.7 kW),
               constant injection times, constant speeds, and constant compression
               ratios.
                   Ziejewski and Kaufman  reported the results of an endurance
                                       23
               test using 25 to 75 percent alkali-refined sunflower oil with diesel and
               25 to 75 percent of safflower oil with diesel on a volume basis. The
               major problems experienced were premature injection, determination
               of nozzle performance, and heavier carbon deposits in the grooves of
               the piston ring. There was no significant problem with engine opera-
               tion when a blend of safflower oil was used. That investigation
               revealed that chemical differences between vegetable oil and diesel
               had a very important influence on long-term engine performance.


               8.1.5  Comparing the Effect of Loads on Biodiesel
                       Performance
                                    24
               Raheman and Phadatare  carried out the experiments with different
               oils and suggested that there were variations of the engine torque with
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