Page 638 - Carrahers_Polymer_Chemistry,_Eighth_Edition
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Polymer Technology                                                           601


                                                    R                             R
                                      R                               R



                                                                          O       O
                                          O         O


                                    HC
                                     3

                                                                 HC
                                                                  3
                              Ethyl acrylate derived unit (18.1)      Butyl acrylate derived unit (18.2)

                    The T  of the copolymer must be below the application temperature to allow diffusion of water
                         g
                 from the latex to occur as it is drying forming the protective fi lm.


                 18.12.1   PROCESSING
                 Many different process are used to apply a thin layer of liquid-melted polymer or polymer solu-
                 tion or dispersion) including rollers, spraying, calendering, and brushing. Here we will look at

                 the industrial application of coatings onto film and sheet-like materials. Figure 18.16 contains
                 examples of general coating processes employed to achieve this. The moving sheet is called a web.
                 In roll coating, Figure 18.16(a), the lower roller picks up the coatings material that then transfers

                 it to the second roller and finally to one surface of the mat. Spacing of the rollers, viscosity of the
                 polymer solution in the dip tank, and roller speed and size control the thickness of the applied
                 coating.





                                         Web
                                                         Web

                                                                                   Blade


                                                     Blade


                                   (a)                              (b)


                                                      Extruder

                                                 Die
                                             Web      Fluid curtain
                                                       (c)


                 FIGURE 18.16  Three principle industrial coatings processes for films and thin sheets—(a) roll coating,
                 (b) blade coating, and (c) curtain coating.






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         K10478.indb   601
         K10478.indb   601                                                                    9/14/2010   3:43:43 PM
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