Page 701 - Carrahers_Polymer_Chemistry,_Eighth_Edition
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664                                                    Carraher’s Polymer Chemistry


                     synthesize needed materials. This awareness also involves realizing that we need to take care of
                     our environment with us being responsible care takers of the world in which we reside.

                 GLOSSARY

                    Anaerobic adhesives: Adhesives that cure or set in the absence of oxygen.
                    Biological compatibility: No negative biological interactions.
                    Bioerodability: Material degradation caused by biological means.
                    Cisplatin (cis-diaminedichloroplatinum II): Most widely used anticancer drug.

                    Doping: Addition of materials that create electron sinks or deficiencies and electron excesses
                      that are necessary to create electrically conductive polymers.
                    Engineering plastics: Also referred to as high-performance thermoplastics or advanced ther-
                      moplastics. An engineering plastic is simply one that can be cut, sawed, drilled, or simi-
                      larly worked with.
                    Excimer: Similar to an exciplex except the complex is formed between like molecules.
                    Exciplex: An excited state complex formed between two different kinds of molecules, one that
                      is excited and the other that is in its grown state.
                    Green materials: Includes materials that do not have a negative impact on the environment;
                      biomass-derived materials.
                    Hydrogels: Cross-linked, hydrophilic polymer networks that allow smaller drugs access to

                      their interior and that can be designed to inflate, swell at the desired site, to deliver a
                      drug.
                    Limiting oxygen index (LOI): Minimum oxygen level where burning is sustained.
                    Magnetostrictive material: Materials that change their dimension when exposed to a magnetic
                      fi eld.
                    Nanowires: Oligomeric molecules that contain an electrical conducting core with chemically
                      functional groups on each end.
                    Nonlinear optics (NLO): Involves the interaction of light with materials resulting in a change
                      in the frequency, phase, or other characteristics of the light.
                    Photochemistry: Area of study involving the interaction of electromagnetic energy that results
                      in chemical reactions.
                    Photoconductive: Material that is conductive when exposed to light.
                    Photophysics: Area of study involving the absorption, transfer, movement, and emission of
                      electromagnetic, light, energy without chemical reactions.
                    Photoresponsive: Material whose properties change when exposed to light.
                    Piezoelectric material: Materials that emit a current when pressure is applied. The pressure
                      may be applied by simply exposing the material to an electromotive force.
                    Shape memory alloys: Materials that change shape and/or volume as they undergo phase
                      changes.
                    Smart materials: Materials that react to applied force—electrical, stress–strain (including
                      pressure), thermal, light, and magnetic.
                    Transdermal: Across the skin.

                 EXERCISES

                 1.  Compare and contrast cancer and healthy cells.
                 2.   Describe a smart material.


                 3.   What are properties that make aromatic fibers good material for fire resistant materials?
                  4.   Which of the following would you expect might become electrically conductive if doped and
                     why? Polyethylene, poly(vinyl chloride), PS, poly-p-phenylene, and PPV.
                  5.   What advantageous might conductive carbon nanotubes have over polyacetylene?






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