Page 443 - Corrosion Engineering Principles and Practice
P. 443

412    C h a p t e r   1 0                                                             C o r r o s i o n   i n   S o i l s   a n d   M i c r o b i o l o g i c a l l y   I n f l u e n c e d   C o r r o s i o n    413


                         Strictly anaerobic environments are quite rare in nature. However,
                      strict  anaerobes  are  commonly  found  flourishing  within  anaerobic
                      microenvironments  (under  deposits  and  fouling)  even  in  highly
                      aerated systems. The pH conditions and availability of nutrients also
                      play a role in determining what type of microorganisms can thrive in
                      a particular soil environment. Another way of classifying organisms
                      is according to their metabolism:
                          •  The  compounds  or  nutrients  from  which  they  obtain  their
                             carbon for growth and reproduction
                          •  The  chemistry  by  which  they  obtain  energy  or  perform
                             respiration
                          •  The elements they accumulate as a result of these processes
                         All microorganisms are not equally aggressive to metals. What is
                      important,  from  a  corrosion  standpoint,  is  the  number  of
                      microorganisms of the specifically corrosive types. Microorganisms
                      associated with corrosion damage are classified as
                          •  Fungi  that  may  produce  corrosive  byproducts  in  their
                             metabolism,  such  as  organic  acids. Apart  from  metals  and
                             alloys these can also degrade organic coatings and wood.
                          •  Slime formers that may produce concentration corrosion cells
                             on surfaces.
                          •  Anaerobic bacteria that produce highly corrosive species as
                             part of their metabolism.
                          •  Aerobic bacteria that produce corrosive mineral acids.

                      Fungi
                      Fungi  can  be  separated  into  yeasts  and  molds.  Certain  fungi  are
                      capable  of  producing  organic  acids  and  have  been  blamed  for
                      corrosion  of  steel  and  aluminum,  as  in  the  corrosion  failures  of
                      aluminum  aircraft  fuel  tanks.  In  addition,  fungi  may  produce
                      anaerobic sites for SRB and produce metabolic byproducts that help
                      the  growth  of  various  bacteria  leading  to  fouling  and  associated
                      corrosion problems. In general, molds are considered to be of greater
                      importance in corrosion problems than yeasts [13].
                      Algae
                      Algae are photosynthetic organisms with relatively simple nutritional
                      requirements of light, water, air and certain inorganic compounds.
                      Algae are found in wide ranges of salinity, from seawater to distilled
                      water, and survive in different degrees of light intensity. Algae have
                      been associated with fouling and related corrosion problems through
                      the photosynthetic production of gaseous oxygen when exposed to
                      light and the production of corrosive species such as organic acids.
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