Page 536 - Corrosion Engineering Principles and Practice
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502    C h a p t e r   1 2                                                                                                        C o r r o s i o n   a s   a   R i s k    503


                       0.99998  Probability of not cracking
                                                                    0.5  Clamp
                                   0.9 Find by inspection
                                                                    0.2  $ Gas plant
                                                                    0.3  $ CCU
                                                                    0.7  Clamp
                                                             Find before   0
                                                          0.5  leak  0.2499  $ Gas plant
                                                                        $ CCU
                      Piping                                        0.05  Fire
                                                 0.7 Autorefrigerate  0.0001  VCE
                                                                    0.5  Clamp
                                                                    0   $ Gas plant
                                                                   0.299  $ CCU
                                              Leak        0.5  Not find  0.2  Fire
                                         0.99 before break          0.001  VCE
                                                                    0.7  Clamp
                       0.00002  Probability                 Find before   0  $ Gas plant
                            of cracking                  0.97  Leak becomes  0.2499  $ CCU
                                                              large  0.05  Fire
                                                      Not           0.0001  VCE
                                     Do not find   0.3  Autorefrigerate  0.5  Clamp
                                  0.1  by                           0   $ Gas plant
                                     inspection                    0.299  $ CCU
                                                         0.03  Not find  0.2  Fire
                                                                   0.001  VCE
                                                                    0.33  Leak/break/no fire
                                                                    0.6  Leak/break/fire
                                         0.01 Break                 0.07  Leak/break/VCE
                      FIGURE 12.13  Event tree analysis that was performed on each process
                      system of a FCCU gas plant ($ = cost of damage, CCU = catalytic cracking
                      unit, VCE = vapor cloud explosion).
                      23 leaks in piping located in the fractionator’s overhead and the wet
                      gas  compression  sections  of  the  FCCU.  Follow-up  with  intensive
                      ultrasonic  (UT)  shear  wave  inspection  located  an  additional  73
                      carbonate cracking like indications in the gas recovery section of the
                      FCCU. As with many forms of SCC, radiography was not considered
                      a suitable inspection technique for carbonate cracking [15].
                         In  petroleum  refining,  carbonate  SCC  can  occur  in  FCCU  gas
                      plants where the process environment contains a significant amount
                      of carbonate/bicarbonate ions, H S, free water, and ammonia. The
                                                   2
                      equipment most likely to be affected in the FCCU gas plant are the
                      main fractionator’s overhead condensers and accumulators, wet-gas
                      compressor’s knockout drums and condenser, deethanizer (or other
                      similar light-end fractionators), and all associated piping including
                      the sour-water streams originating from these areas. In this example,
                      probabilities were based on the occurrence of the event in any given
                      year. Values assigned for the probabilities were determined using the
                      number of welds that cracked divided by the total number of welds
                      in the system. Consequences included
                          •  Leaks/breaks
                          •  Using clamps to contain the leak
                          •  Shut down of the unit (SID)
                          •  Fire
                          •  Vapor cloud explosion (VCE)
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