Page 539 - Corrosion Engineering Principles and Practice
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                      that are small leaks which, once detected, can be readily contained
                      and mitigated without causing a significant incident. These are often
                      the result of pinholes due to localized corrosion or small, tight cracks
                      that only allow minor fluid seepage. On the other hand, some breeches
                      of  containment  are  the  result  of  major  ruptures  that  allow  large
                      quantities of hazardous fluid to escape in a short period of time. It is
                      difficult and sometimes impossible to react quickly enough to contain
                      and mitigate such releases without enduring significant incidents.
                         Corrosion  and  materials  engineering  expertise  is  required  to
                      estimate the size and nature of damage that could result in a plant
                      item. As described in Chap. 6, different corrosion mechanisms can
                      produce different damage morphologies. The difference in impact on
                      the release rate created at a pinhole leak versus that of a large rupture
                      is a good example of this aspect of consequence sensitivity.
                         Another important field covered by corrosion engineering is that
                      of  materials  properties.  For  example,  the  risk  of  a  catastrophic
                      explosion from cracks in a brittle material associated with high release
                      rates  is  obviously  greater  than  in  a  material  with  higher  fracture
                      toughness.  The  toughness  of  a  material  is  a  key  parameter  in
                      determining  so-called  “leak-before-break”  safety  criteria  and  the
                      general  tolerance  toward  defects.  An  understanding  of  how  the
                      toughness of a material can be reduced in service over time is thus
                      obviously important [3].
                      12.6.3  Application of Risk-Based Inspection
                      The application of RBI becomes most effective when it involves the
                      efforts of a multidiscipline team from operations, process engineering,
                      equipment specialists, and maintenance in addition to inspection and
                      corrosion engineers. As a team, these experts can exchange valuable
                      information and use the team synergy to arrive at a mutually agreeable
                      approach to risk reduction that may involve approaches other than
                      increased inspection. The following sections describe three approaches
                      to reduce the risk of operating plant equipment that are incorporated
                      into the API RBI program [16].
                      Optimizing Inspection/Monitoring
                      Once the risk assessment has been completed, the results are used to
                      evaluate  the  effectiveness  of  the  present  inspection/monitoring
                      strategy while looking for ways to optimize the strategy and reduce
                      the overall risk of continued operation. For equipment identified as
                      high risk, changes in the detailed inspection plan that would reduce
                      the risk should be considered. For equipment identified as low risk,
                      changes in the detailed inspection plan that would reduce costs while
                      not increasing risk appreciably should be considered [3].
                         The  RBI  assessment  identifies  the  potential  deterioration
                      mechanisms that can lead to failure in each piece of equipment. It is
                      very important to determine whether the existing inspection plan is
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