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408  Chapter 9 Operation Optimization
                  The4 following variance of the validated measured variables are obtained:
                          m
                                   2
                  var (X i )=  P  …N i;j W j;j † …X †
                                      0
                                     j
                          jˆ1
                for the estimated unmeasured variables:
                          m
                                    2
                  var (Y i )=  P  …N n‡i;j W † …X †
                                       0
                                   j;j
                                       j
                          jˆ1
                  Taking into account:
                  var (X¢ j )=1/W jj
                now:
                          m
                              2
                  var (X i )=  P  N =…X †
                                 0
                                 j
                             i;j
                          jˆ1
                          M
                  var (Y i )=  P  N 2 n‡i;j  =var…X †
                                     0
                                     j
                          jˆ1
                  The contribution of the variance of measurement k in the estimation of the var-
                iance of reconciled state variable i is derived from the equation above:

                                           0
                                 var…X i †var…X †
                  Contribution k,i =       k
                                   …M †i; k 2
                                      1
                  The sensitivity coefficient relating the validated variable to the measured value
                and the standard deviation are:

                  DerVal k,i =  dX k  DerAcc k,i =  dX k
                            dX i           d  i
                  The analysis technique to determine the accuracy of the reconciled data has been
                developed by Heyen (1994)and further extended by Heyen et al. (1996).
                References
                Albers J.C. On line data reconciliation and  Belsim. Alee des Noisetiers B4301 Angleur
                  error detection. In: Advanced Process  Liege Belgium E-mail:
                  Control and Information Systems for the  hotline@belsim.arc.be User Group
                  Process Industries (Kane, L.A., Ed.), Gulf  Meeting, Antwerp, April 1994.
                  Publishing Company, 1999, pp. 136±139.  Britt, H.I. and Luecke, R.H. The estimation of
                  ISBN 0-88415-239-1.               parameters in nonlinear implicit models.
                Albers J.C. Data reconciliation with  Technometrics 1973, 15, 233±247.
                  unmeasured variables In: Advanced Process  Factora F.C., Gochenour, G.B., Houk, B.G.
                  Control and Information Systems for the  and Kelly, D.N. Closed loop real time
                  Process Industries (Kane, L.A., Ed.), Gulf  optimization and control of a world scale
                  Publishing Company, 1999, pp. 140±142.  olefins plant. Lyondell PetroChem Co. &
                  ISBN 0-88415-239-1.               DMC Corp., AIChE meeting, Spring 1992.
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