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degree    The number of edges incident to a
                                                           node; here notated as d(v).
                                                              Comment: The number of reactions in which
                                 D                         a compound participates is its degree. Simi-
                                                           larly, the number of compounds participating in
                                                           a reaction is the degree of the reaction. Since the
                                                           best-known biochemical network described has
                  dalton   The unit of molecular weight, in
                                                           an enzyme for every reaction, one usually means
                  g/mol.
                                                           nonenzymatic degree, when applying the word
                    Comment: A mole (abbreviated mol) is an
                                                           to reactions. Note this would not be the case for
                 Avogadro’s number (N) of molecules, approxi-  other versions of the biochemical network which
                  mately equal to 6.02252 × 10 23  molecules/mol.
                                                           includespontaneousreactions, ordetailedkinetic
                  Darboux’s theorem    On any symplectic   and mechanistic views of reactions in which the
                  manifold (M, ω) there exist local coordi-  enzyme does not necessarily appear in the reac-
                                                      n
                                                1
                  nates (canonical coordinates) (x ,...,x ,  tion equations as a formal catalyst.
                   1
                         n
                  y ,...,y ) in which the symplectic form ω
                                                           degree of polymerization  The number of
                  takes the form
                                                           monomeric units in a macromolecule or oligomer
                                  n
                                                           molecule,a block,ora chain.
                                           i
                                      i
                             ω =    dx ∧ dy .
                                 i=1                       degreesoffreedom    AsystemofN particles,
                  dark current  See responsivity.          free from constraints, has 3N independent coor-
                                                           dinates (positions and momenta) called degrees
                  dark output   See responsivity.
                                                           of freedom.
                  dark resistance  See responsivity.
                                                           delocalization  A quantum mechanical con-
                  data model   A computational method for  cept most usually applied in organic chemistry
                  implementing a domain model.             to describe the π-bonding in a conjugated sys-
                    Comment: This is the database management  tem. This bounding is not localized between two
                  system, object-oriented model, set of MatLab  atoms: instead, each link has a “fractional double
                  functions, etc., which [reify] the ideas in the  bond character” or bond order. There is a cor-
                  domain model. Thus, it is the computational  responding “delocalization energy,” identifiable
                  machinery, not (per se) the intellectual basis of  with the stabilization of the system compared
                  the abstract model of the domain.        with a hypothetical alternative in which formal
                                                           (localized) single and double bonds are present.
                  decreasing function  A function f(x) such  Some degree of delocalization is always present
                  that f(y) ≤ f(x) whenever x ≤ y.         andcanbeestimatedbyquantummechanicalcal-
                  definite integral  Let f be a function defined  culations.
                  on a closed interval [a, b] and P a partition a =
                                                           delta function  See Dirac delta function.
                  x <x <x < ··· <x = b of [a, b]. Let |P |
                                     n
                           2
                       1
                   0
                  denote the length of the longest subinterval in the  dense  A subset S in a space X is dense (in
                                                                         ¯
                  partition P and let ¯x ∈ [x  ,x ] be arbitrary. If  X ) if its closure S = X.
                                 i    i−1  i
                  the limit

                                                           denser subgraph   A subgraph G of the bio-
                                n
                                                           chemical network such that the degree of each
                           lim    f(¯x )(x − x i−1 )
                                     i
                                        i
                          |P |→0                           reaction node v  is greater than or equal to x,
                               i=1                                      r,i
                                                           and the degree of each compound node v m,j  is
                  exists, f is called (Riemann) integrable and
                                                           less than or equal to y; that is, d(v ) ≥ x,
                                                                                          r,i
                                      n
                      b                                    d(v m,j ) ≤ y.
                       f(x)dx = lim     f(¯x )(x − x i−1 )    Comment: Because any two denser subgraphs
                                              i
                                           i
                                |P|→0
                     a
                                     i=1                   formed with the same values of x and y are not
                  is called the definite integral (or Riemann inte-  necessarily isomorphic, denser subgraphs are not
                  gral) of f from a to b.                  necessarily motives. Familarly known as a blob.
           © 2003 by CRC Press LLC
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