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Dini’s theorem   Let {f } be a sequence of  Dirac operator  A linear first-order partial
                                       n
                 continuous  functions  converging  pointwise  to  differential  operator  with  nonconstant  coeffi-
                 a  continuous  function  f . If {f }  is  monotone  cients, defined between sections of the spin bun-
                                          n
                 increasing sequence, then the convergence is uni-  dle. It is defined as covariant derivative followed
                 form.                                     by Clifford product. Locally the Dirac operator
                                                           is given by
                 dipole–dipole  interaction  Intermolecular
                                                                                  δ
                 or intramolecular interaction between molecules      Dψ =    γ µ    ψ
                                                                                   m
                 or  groups  having  a  permanent  electric  dipole         µ    δx u
                 moment. The strength of the interaction depends  µ
                                                           where γ are the Dirac gamma matrices.
                 on  the  distance  and  relative  orientation  of  the
                 dipoles.  The term applies also to intramolecu-
                                                           Dirac spinors  Elements in the full complex
                 lar interactions between bonds having permanent
                                                           spin representation as opposed to elements in the
                 dipole moments.
                                                           half  spin  representation  which  are  called Weyl
                                                           spinors and elements in the real spin representa-
                 Dirac   Paul  Adrien  Maurice  Dirac  (1902–
                                                           tion which are called Majorana spinors.
                 1984),  Swiss/English  theoretical  physicist,
                 founder  of  relativistic  quantum  mechanics.
                                                           directed  edge  A  sequence  of  two  nodes
                 Nobel  prize  for  physics  1933  (shared  with
                                                           (ordered  pair)  in  a  graph;  often  denoted
                 Schr¨odinger).
                                                           /v , v i+1 0.
                                                            i
                                                             Comment: These are the edges that are drawn
                 Dirac delta function  The generalized func-
                 tion δ(x − x ) defined by                  with arrows, indicating a direction of travel or
                           0                               flow. See edge.

                         ∞
                           f (x)δ(x − x )dx = f (x ).      direction  In a formal reaction equation, the
                                               0
                                     0
                                                           consumption of sinistralateral coreactants (the
                        −∞
                 Dirac  delta  measure  The  measure  δ y  “forward” direction); equally, the consumption
                                                    n
                 located at some arbitrary,  but fixed y ∈ R is  of dextralateral coreactants (the “reverse” direc-
                               n
                 defined for A ⊂ R as                       tion).
                                                             Comment:  Chemical  and  biochemical  reac-

                                   1 if y ∈ A
                          δ (A) =                          tions can be thought of as a composite of two
                           y
                                   0 if y  ∈ A.            reactions. One that consumes sinistralateral core-
                                                           actants, producing dextralateral ones or proceed-
                 Dirac equation  The equation
                                                           ing left to right and the opposite. These two
                             (i   ∂ − m)ψ = 0              directions are often represented as half reactions
                                                           which are formal equations that specify only
                 where ψ is a wave function describing a relativis-  one of the two directions. The intrinsic rates of
                                             µ
                 tic particle of mass m and   ∂  := γ δ with γ  µ  the two directions, as measured by their respec-
                                               µ
                 the Dirac gamma matrices.                 tive rate constants can differ very significantly.
                                                           See also dextralateral, dynamic equilibrium, for-
                 Dirac gamma matrices   The 4 × 4 matrices
                                                   j       mal reaction equation, microscopic reversibility,
                           I  0                0  σ
                  0                  j                     product, rate constant, reversibility, sinistralat-
                 γ   =           ,  γ   =        j    ,
                           0 −I               −σ   0       eral, and substrate.
                 j = 1, 2, 3, where I is the 2 × 2 identity matrix

                      j                     1     01       Dirichlet boundary condition  Specifica-
                 and  σ are  the  Pauli  matrices  σ  =  ,
                                                  10       tion of the value of the solution to a partial dif-

                       0 −i         10                     ferential equation along a bounding surface.
                  2            1           2
                 σ =         , σ =        , i = −1.
                       i  0         0 −1
                                                           Dirichlet problem  The problem of finding
                 Dirac  Laplacian  The  square  root  of  the  solutions of the Laplace equation  u = 0(u +
                                                                                             xx
                                           2
                 Dirac operator, i.e., we have   D ψ =  ψ, the  u  = 0 in two dimensions) that take on given
                                                            yy
                 d’Alembert operator.                      boundary values.
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