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P1: JPJ/FFX  P2: FCH/FFX  QC: FCH/FFX  T1: FCH
            0521820928c05  CB644-Petlyuk-v1                                                      June 11, 2004  20:15





                        136    Distillation Trajectories and Conditions of Mixture Separability


                                                           2
                                     x D
                                                    (K )
                                                      23
                                                   (K )
                                                    22
                                                  (K )          N +
                               x F                 21            3
                                          a)
                                                                    +
                                     x B                           N 2
                                                                      +
                                                                     N 1

                                                      (L/V) 1
                                                                 (L/V) 2
                                                 (K )
                                                   21
                                                                   (L/V) 3
                                       1           x D           13           3
                                                         S 1  S 2  S 3
                                                            2


                                          b)




                                                                +
                                                              N qsh




                                                                        pinch
                                                                    L (  V )
                                                          SN qsh
                                                    x D
                                        1                                       3
                                                                 13
                               Figure 5.18. The tangential pinch in rectifying section for the
                               acetone(1)-benzene(2)- chloroform(3) mixture for the split 1,3 : 2: (a)
                                                                  (3)
                               sharp separation (the tangential-pinch region Reg tang  not shaded), (b)
                               quasisharp separation. 1, 2, 3, different values of L/V and different
                               iso-K 2 lines (thin lines); SN, saddle-node point.


                               nonmonotony leads to “tangential pinch.” Figure 5.18 shows the region Reg tang
                               (it is not shaded), where points N are absent at any points of the top product
                                                            +
                               located at side 1-3 and at any values of parameter L/V (pinch region Reg tang ).


                        5.4.3. The Product Is a Three-Component Mixture (k = 3)

                               Three-component mixture is a separation product of initial three-component mix-
                               ture at nonsharp separation.
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