Page 181 - Drilling Technology in Nontechnical Language
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172             Drilling Technology in Nontechnical Language Second Edition






                  Hydrogen  sulfide–related  problems.  Hydrogen  sulfide  (H S)  may


                                                                           2
              enter the mud from a permeable formation, either as a kick or from within
              drilled cuttings. Apart from the extreme toxicity of this gas, it causes
              hydrogen embrittlement of most steels, which degrades tensile strength.
              If H S is anticipated, an excess level of lime in the mud will help. The
                  2
              alkaline lime will help neutralize the acidic H S. The reaction forms active
                                                        2

              sulfides such as CaS or Ca(HS) , which will liberate H S if exposed to a
                                                                  2
                                            2
              mild acid. Once H S has been identified in the mud system, zinc oxide

                                2
              (ZnO) may be added. ZnO is an effective scavenger of H S and active
                                                                      2

              sulfide salts. This reacts to form stable zinc sulfide. It is not recommended


              to use ZnO before H S is identified, as it will mask a slow entry of H S into
                                                                             2
                                 2
              the system. Recommended concentration of ZnO is around 2 lb for each
              barrel of mud.
                                         Summary
                  This chapter covered one of the most important systems on the rig

              for safe and efficient drilling—the drilling fluids. First the functions of


              a drilling fluid were listed, and then seven distinct classifications of mud


              were described. Drilling fluid design was covered in some detail for the
              physical, rheological, and chemical requirements.































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