Page 8 - Elements of Chemical Reaction Engineering 3rd Edition

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X Contents

6.2 Maximizing the Desired Product in Series Reactions 291
6.3 Algorithm for Solution to Complex Reactions 295
6.3.1 Mole Balances 295
6.3.2 Net Rates of Reaction 296
6.3.3 Rate Laws 297
6.3.4 Stoichiometry: Relative Rates of Reaction 297
6.3.5 Stoichiometry: Concentrations 300
6.3.6 Combining Step 301
6.3.7 Multiple Reactions in a CSTR 307
6.4 Sorting It All Out 314
6.5 TheFunPart 315
6.6 The Attainable Region CD-ROM 316
Summary 318
Questions and Problems 320
Journal Critique Problems 335
CD-ROM Material 335
Supplementary Reading 336

7 NONELEMENTARY REACTION KINETICS 339

7.1 Fundamentals 340
7.1.1 Active Intermediates 340
7.1.2 Pseudo-Steady-State Hypothesis (PSSH) 342
7.2 Searching for a Mechanism 344
7.2.1 General Considerations 344
7.2.2 Reaction Pathways 352
7.3 Polymerization 354
7.3.1 Step Polymerization 356
7.3.2 Chain Polymerizations Reactions 360
7.3.3 Modeling a Batch Polymerization Reactor 368
7.3.4 Molecular Weight Distribution 370
7.3.5 Anionic Polymerization 375
7.4 Enzymatic Reaction Fundamentals 383
7.4.1 Dejhitions and Mechanisms 383
7.4.2 Michaelis-Menten Equation 386
7.4.3 Batch Reactor Calculations 389
7.4.4 Inhibition of Enzyme Reactions 391
7.4.5 Multiple Enzyme and Substrate Systems 392
7.5 Bioreactors 393
7.5.1 Cell Growth 394
7.5.2 Rate Laws 396
7.5.3 Stoichiometry 398
7.5.4 Mass Balances 400
7.5.5 Chemostats 404
7.5.6 Design Equations 404
7.5.7 Wash-out 406