Page 8 - Elements of Chemical Reaction Engineering Ebook

Contents ix

4.7.1 Startup of a CSTR 189
4.7.2 Semibatch Reactors 190
4.7.3 Reactive Distillation 197
4.8 Recycle Reactors 200
Summary 202
ODE Solver Algorithm 204
Questions and Problems 205
Journal Critique Problems 219
Some Thoughts on Critiquing What You Read 220
CD-ROM Material 220
Supplementary Reading 222

5 COLLECTION AND ANAL'YSIS OF RATE DATA 223

5.1 Batch Reactor Data 224
.5.1.1 Differential Method of Rate Analysis 224
.5.1.2 Integral Method 235
5.2 Method of Initial Rates 239
5.3 Method of Half-Lives 242
5.4 Differential Reactors 243
5.5 ]Least-Square Analysis 250
.5.5.1 Linearization of the Rate Law 250
5.5.2 Nonlinear Least-Squares Analysis 252
.5.5.3 Weighted Least-Squares Analysis 261
5.6 ]Experimental Planning (CD-ROM) 262
5.7 ]Evaluation of Laboratory Reactors (CD-ROM) 263
5.7.1 Integral (Fixed-Bed) Reactor 264
-5.7.2 Stirred Batch Reactor 264
5.7.3 Stirred Contained Reactor (SCSR) 265
-5.7.4 ]Continuous-Stirred Tank Reactor (CSTR) 265
5.7.5 Straight-Through Transport Reactor 266
5.7.6 Recirculating Transport Reactor 266
5.7.7 Summary of Reactor Ratings 267
!summary 268
Questions and Problems 269
Journal Critique Problems 279
CD-ROM Material 280
Supplementary Reading 280

6 MULTIPLE REACTIONS 2;82

6.1 Maximizing the Desired Product in Parallel Reactions 284
ti. 1.1 Maximizing the Rate Selectivity Parameter S
jbr One Reactant 285
6.1.2 Maximizing the Rate Selectivity Parameter S
for Two Reactants 288