Page 167 - Encyclopedia of Chemical Compounds 3 Vols
P. 167

BORIC ACID












                 Hydrogen orthoborate. Red
               atoms are oxygen; white atoms
               are hydrogen; and yellow atom
                      is boron. PUBLI S H E R S
                        RESOURCE GROU P























                                       the German chemist Wilhelm Homberg (1652–1715), who in
                                       1702 treated natural borax (Na 2 B 4 O 7 10H 2 O) with acid to
                                       obtain a product he called sedative salt, probably a form of
                                       boric acid. The chemical structure of the compound was
                                       determined in 1808 by the French researchers Louis-Joseph
                                       Gay-Lussac (1778-1850) and Louis-Jacques The ´nard (1777–
                                       1857).


                                       HOW IT IS MADE
                                          The most common method of producing boric acid is
                                       by treating the relatively abundant borax with hydrochlo-
                                       ric or sulfuric acid and crystallizing out the boric acid
                                       that forms in the reaction. A less common method of
                                       preparation involves the treatment of borax brine solu-
                                       tions with a chelating agent that binds to the borates
                                       present in the brine, which can then be converted to
                                       boric acid.


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