Page 88 - Encyclopedia of Chemical Compounds 3 Vols
P. 88

CH 3
                                                                                H   H    C   CH 3
                                                                          CH H     C   C     H
                                                                            3
                                                                   H   H    C   C      H   H

                                               H             CH H     C   C     H   H
                                                               3
                                       CH
                                         3                                    H
                                                        H H    C   C      H
                              HO       C      C       H
                                   C       C      C H    C   C     H   H
                                              H
                                                H            H   H
                                   C       C      C   C
                             H C       C      O       CH   H
                               3                        3
                                       CH 3

                    OTHER NAMES:
                    See Overview.

                        FORMULA:
                         C 29 H 50 O
                       ELEMENTS:
                Carbon, hydrogen,        Alpha-Tocopherol
                         oxygen

                  COMPOUND TYPE:
                         Organic
                          STATE:  KE     OVERVIEW
                          Liquid
                                             Alpha-tocopherol (AL-fa toe-KOF-er-ol) is also known
                MOLECULAR WEIGHT:  Y     as 2,5,7,8-tetramethyl-2-(4,8,12-trimethyltridecyl)chroman-
                                         6-ol and 3,4-Dihydro-2,5,7,8-tetramethyl-2-(4,8,12-trimethyl-
                    430.69 g/mol F
                                         tridecyl)-2H-1-benzopyran-6-ol, as well as by many other
                   MELTING POINT:  A
                                         systematic names. It is one of a family of compounds, the
                                         tocopherols, that makes up vitamin E. Other members of the
             2.5 Cto3.5 C(36 Fto C
                                         family include the beta (b), gamma (g), delta (d), and epsilon
                           38 F) T
                                         (E) tocopherols. All tocopherols share the same basic molecu-

                    350 C (660 F;
                    BOILING POINT: S
                                         lar structure, differing only in slightly different arrange-
                     decomposes)
                                         ments of methyl (CH 3 -) and hydroxyl (OH-) groups. In terms
                      SOLUBILITY:        of biological activity, a-tocopherol is the most important
                Insoluble in water;      member of the tocopherol family. The tocopherols are all pale
                soluble in alcohol,      yellow, viscous oils found in a variety of plants, including
               ether, acetone, oils,
                                         almonds, mustard greens, green and red peppers, spinach,
                 and most organic
                                         and sunflower seeds. The most important source for the
                         solvents
                                         vitamin is wheat germ.
                                             Vitamin E was discovered in 1922 by two scientists at the
                                         University of California at Berkeley, Herbert McLean Evans
                                         CHEMICAL COMPOUNDS                                   37
   83   84   85   86   87   88   89   90   91   92   93