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APPENDIX E  Origins of the Complex Permittivity     571



                                                        res







                                                                    res











                                Figure E.2 Plots of the real and imaginary parts of the
                                resonant susceptibility, χ res ,as given by Eq. (E.20). The
                                full-width at half-maximum of the imaginary part, χ ,is

                                                                    res
                                equal to the damping coefficient, γ d .
                     Key features to note in Figure E.2 include the symmetric χ function, whose full-

                                                                     e

                     width at its half-maximum amplitude is γ d . Near the resonant frequency, where χ res
                     maximizes, wave attenuation maximizes as seen from Eq. (44), Chapter 11. Addi-
                     tionally, we see that away from resonance, attenuation is relatively weak, and the
                     material becomes transparent. As Figure E.2 shows, there is still significant variation

                     of χ res  with frequency away from resonance, which leads to a frequency-dependent
                     refractive index; this is expressed approximately as
                                        .

                                     n =   1 + χ res  (away from resonance)        (E.22)
                     This frequency-dependent n, arising from the material resonance, leads to phase and
                     group velocities that also depend on frequency. Thus, group dispersion, leading to
                     pulse-broadening effects as discussed in Chapter 12, can be directly attributable to
                     material resonances.
                         Somewhat surprisingly, the classical “spring model” described here can provide
                     very accurate predictions on dielectric constant behavior with frequency (particularly
                     off-resonance) and can be used to a certain extent to model absorption properties. The
                     model is insufficient, however, when attempting to describe the more salient features
                     of materials; specifically, it assumes that the oscillating electron can assume any one
                     of a continuum of energy states, when, in fact, energy states in any atomic system are
                     quantized. As a result, the important effects arising from transitions between discrete
                     energy levels, such as spontaneous and stimulated absorption and emission, are not
                     included in our classical spring system. Quantum mechanical models must be used
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