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EOR mechanisms of wettability alteration and its comparison with IFT  233


                45
                40
               %
               ,                                                 IFT=0.049 mN/m
               n
               o  35
               i
               t
               a
               r
               e
               t  30
               l
               a
               t
               e
               w  25
               m
               o
               r  20
               f
               F
               R
               l
               a  15
               t                                                IFT=0.0323 mN/m
               n
               e
               m  10
               e
               r
               c
               n
               I                                                IFT=0.0088 mN/m
                 5
                 0
                   0       20      40      60      80      100      120     140
                                             Time, day
              Figure 9.10 Effect of wettability alteration on oil recovery by spontaneous imbibition
              at different IFT values.
                50
                45
                                                                IFT=0.0088 mN/m
                40
               %
               ,
               n  35
               o
               i
               t                                                IFT=0.0323 mN/m
               a
               r  30
               e
               t  l
               a
               t  25
               e
               w
               t
               u  20
               o
               h
               t
               i
               w  15
               F
               R
                10
                 5
                                                                IFT=0.049 mN/m
                 0
                   0       20      40      60      80      100      120     140
                                             Time, day
                         Figure 9.11 Effect of IFT without wettability alteration.
              recovery but mitigate wettability alteration mechanism. The resultant effect
              will be the balance of the two negative and positive effects.
                 Xie et al. (2005) compared the spontaneous imbibition rates using
              nonionic poly-oxyethylene alcohol (POA) and cationics (CAC). The IFT
              of POA solution was 19 times higher than of CAC solution (5.7 vs.
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