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Spontaneous imbibition                                       287







































               Figure 10.3 Surfactant phase saturation for 122 mD and 0.24 porosity at 20 days.

              surfactant cannot diffuse into the low-permeability rock as fast as in the
              high-permeability rock, although the capillary pressure is 412 times higher.
              A higher capillary pressure means higher imbibition force, and thus higher
              imbibition rate. However, there is another force: viscous force. We need to
              consider these two forces together.

              10.3.2 Theoretical considerations
              According to Eq. (10.1), the imbibition velocity into a smaller pore is lower
              than that into a larger pore. A core of smaller radii has lower permeability as r
                             p ffiffiffiffiffiffiffiffi
              is proportional to  k=f. Although the capillary force is high in a shale core,
              the viscous force is also high; the resultant effect of two forces makes the
              imbibition velocity in a low-permeability rock lower than that in a high-
              permeability rock.
                 Note that Eq. (10.1) ignores the slip flow. For the slip flow to take place,
              the capillary diameter needs to be smaller than approximately 3 nm (Sharp
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