Page 428 - Enhanced Oil Recovery in Shale and Tight Reservoirs
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     396                            Enhanced Oil Recovery in Shale and Tight Reservoirs
          may help to remove such blockage. However, several factors need to be
          considered: fine migration, fracture closure, etc. Water blockage is more
          severe near the fracture face. To effectively remove this blockage, early
          flow back should be practiced. Here it means that if you plan to perform
          flow back, early flow back is preferred, because as time elapses, the water
          may enter deep into the formation and then it will be more difficult to
          flow back. You may argue that this deep dissipation may mitigate the water
          blockage. This issue has been discussed earlier.
          12.9.3 CO 2 injection
          CO 2 dissolves in trapped water and reduces the gas-water interfacial tension.
          Then the energized water will more easily flow out.
          12.9.4 Solvent injection
          Injection of a mutual solvent like methanol experienced success in gas res-
          ervoirs. Heavier alcohols like isopropanol, butanol (Sharma and Sheng,
          2017) are preferred for oil reservoirs.
          12.9.5 Use of surfactants
          Fig. 12.54 compares the water saturation profiles during flow back. In the
          experiments, pentane was injected to displace the invaded water from the
          other end of the core. For the left column, the invaded fluid was water
          only. For the right column, different types of microemulsions were formed
          in situ during invasion. First, during water invasion, the saturation in the
          invaded zone was flat which represented the front saturation, For surfactant
          solutions, the water saturation near the fracture face (end of core) was high
          and declined to the front water saturation. Water blocking near the fracture
          face will be more effective. The water saturations in this figure show that
          water blocking will be more severe initially when surfactants are added.
             In Fig. 12.55, the left column shows the average water saturations in the
          corresponding cores presented in the earlier figure. Initially, the water
          saturations with surfactants were higher than those without surfactants.
          But during the flow back, the water saturations with surfactants quickly
          declined to levels lower than those without surfactants. Among all three sur-
          factant cases, the type-I microemulsion triggered the most flow back. Note
          that the type II had a lower viscosity because the pentane oil viscosity was
          about 0.24 cP that was lower than water viscosity, so that it is easier for
          the type II solution fingered through the water phase, being less effective





