Page 234 - Environmental Control in Petroleum Engineering
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220   Environmental Control in Petroleum Engineering


 concentrations obtained by the two agencies for many important waste
 constituents. Further, the correlation was not improved by sending
 samples to different laboratories. Unfortunately, insufficient data were
 obtained to determine the exact cause of the poor correlation.
   An important step in any cleanup program is to determine when
 cleanup is complete. This includes determining the acceptable level
 of residual contaminants. Acceptable levels are typically determined
 by comparing the contaminant levels to the standards for "clean" water
 or to levels that existed prior to the release. These levels are normally
 site-specific and are determined by negotiation with the appropriate
 regulatory agencies (Cooper and Hanson, 1990). Determining cleanup
 levels may require risk assessment studies to be conducted.
   Because of the statistical variability in any data and possible prob-
 lems with sampling and analysis, identifying when a particular stand-
 ard has been achieved can be difficult. Remediation to where the
 applicable standard is met with a 90% confidence limit is often used,
 although the actual level required is normally determined through
 negotiation with applicable regulatory agencies on a case-by-case basis
 (Hoffman, 1993).
   In determining whether further remediation is required, political and
 institutional pressures that have no relevance to protecting human
 health or the environment often exist. Too often these pressures are
 not based on accurate scientific information and can result in additional
 remediation costs with little benefit to the environment. This problem
 is further compounded by the disagreement on what scientific stand-
 ards should be used. Even the relatively simple question of whether
 cleanup should be based on the level of total petroleum hydrocarbons
 or the levels of individual hydrocarbon compounds has not been
 resolved. In some cases, the actual risk to the environment often
 depends more on the composition of a contaminant than on its total
 amount, particularly when only trace quantities are present. The
 importance of accurate scientific information is evidenced in the
 conflicting stories about the environmental impact related to the Exxon
 Valdez spill (Maki et al., 1993).

 8.2 REMEDIATION PROCESSES


   A number of remediation processes are available to clean up con-
 taminated sites (Sims, 1990). Some are suitable for cleaning up
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