Page 102 - Fiber Fracture
P. 102

FRACTURE PROCESSES IN FINE SILICON CARBIDE FIBRES                    87

             CONCLUSION

               The  fracture morphologies of  the  fine  silicon carbide  fibres made  from  polymer
             precursors reveal the nature of their microstructures of the fibres. Successive generations
             of fibres have been created with reduced oxygen contents so producing better controlled
             microstructures and eliminating the presence of  amorphous intergranular phases which
             limit mechanical behaviour at high temperatures. As a consequence the Sic grains have
             become larger and the Young moduli have increased. Whereas the earliest Sic fibres had
             Young moduli of around 200 GPa and showed glassy fracture morphologies because of
             their nanometric grain structure, the latest, near-stoichiometric fibres have moduli of up
             to 400 Gpa and fail with a granular fracture morphology reflecting the large Sic grains
             of their structures.


             REFERENCES

             Berger, M.H., Hochet, N. and Bunsell, A.R. (1995) J. Microsc., 177: 230-241.
             Berger, M.H., Hochet, N. and Bunsell, A.R. (1997) J. Microsc., 185: 243-258.
             Bunsell, A.R. and Berger, M.H. (1999) Fine Ceramic Fibres. Marcel Dekker, New York, NY.
             Fitzer, E. and Heine, M. (1988) In: Fibre Reinforcementsfor Composite Materials, pp. 73-148,  A.R. Bunsell
               (Ed.). Elsevier, Amsterdam.
             Le Coustumer, P., Monthioux, M. and Oberlin, A. (1993) J. Eur: Ceram. SOC., 11: 95-103.
             Shibuya, M. and Yamamura, T. (1996) J. Mater: Sci., 31: 3231-3235.
             Simon, G. and Bunsell, A.R. (1984) J. Mater  Sci., 19: 3658-3670.
             Takeda, M., Imai, Y.,  Ichikawa, H. and Ishikawa, T. (1991) Ceram. Eng. Sci. Pmc., 12: 1007-1018.
             Yajima, S., Hayashi, J. and Omori, M. (1975) Chem Lett., 9: 931-934.
             Yajima, S., Hasegawa, Y., Hayashi, J. and Iimura, M. (1978) J. Marer: Sci., 13: 2569-2576.
             Yajima, S.,  Iwai, T., Yamamura, T.,  Okamura, K. and Hasegawa, Y.  (1981) J. Marer: Sci., 16: 1349-1355.
             Yamamura,  T.  (1993) In:  Proceedings of  the  Euro-Japanese  Colloquium on  Ceramic  Fibres,  ECCM  6,
               Bordeaux, pp.  187-201.
   97   98   99   100   101   102   103   104   105   106   107