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            ORGANIC MATTER‐RICH SHALE DEPOSITIONAL
            ENVIRONMENTS




            João Trabucho‐Alexandre      1,2
            1  Department of Earth Sciences, University of Durham, Durham, UK
            2  Institute of Earth Sciences Utrecht, Utrecht University, Utrecht, The Netherlands




            2.1  INTRODUCTION                                      protozoans (agglutinated forams) build their tests by
                                                                 cementing terrigenous and other particles with an organic
            Shale is the most abundant rock type available at the   ligand. Some quartz silt aggregates in shales  represent the
              surface of our planet and makes up about two‐thirds of   collapsed or compacted tests of these   organisms (Pike
            the  stratigraphic record (Garrels and Mackenzie, 1969).   and Kemp, 1996; Schieber, 2009). When a shale is char-
                           1
            The term “shale”  refers to all sedimentary rocks com-  acterized by an organic matter content higher than the
                                    2
            posed predominantly of mud  (>4ϕ or <0.0625 mm) par-  average marine shale (ca. 0.5%,  Arthur, 1979), it is
            ticles  (cf.  Tourtelot,  1960, p. 342). Mud  particles may be   referred to as an organic matter‐rich shale or, more com-
                                                                                    3
              terrigenous, biogenous, or hydrogenous. Terrigenous—or   monly, a black shale.  Hydrogenous mud   precipitates
              siliciclastic—mud is always detrital, that is, produced by   out  of solution directly, either from seawater or from
            weathering and erosion of preexisting rocks, and comes   interstitial water during  diagenesis, and it includes oxides
            into the depositional environment as individual particles   and hydroxides, silicates, for example,   zeolites and
            and/or  as  aggregates.  Biogenous  mud  is  made by  organ-  clay minerals, heavy metal sulfides, sulfates,  carbonates,
            isms, and includes a skeletal and an organic component.   and phosphates. Clay minerals are therefore not only
            Skeletal mud may be calcareous or siliceous. Some benthic     terrigenous, but they may also be hydrogenous, that is,
                                                                 formed in situ. Biogenous and hydrogenous mud may be
                                                                 detrital, that is, recycled from older deposits, in which
            1  Although the original meaning of the word “shale” is “laminated clayey   case their origin is biochemical, but their texture will be
            rock,” our historical usage of the word has been that of “general class of   clastic. The composition of the detrital fraction of a shale
            fine‐grained sedimentary rocks” (Tourtelot, 1960). There is no reason why
            we should restrict our usage of the word shale to laminated and/or fissile   depends on the petrology of its source areas and on
            fine‐grained sedimentary rocks. “Lamination” has a descriptive and a ge-  the  intensity and effectiveness of chemical weathering.
            netic definition with distinct sedimentologic implications (cf. McKee and
            Weir, 1953; Campbell, 1967), and fissility is a secondary property largely
            related to weathering (e.g., Ingram, 1953). If we define shale as a fissile   3  Modern organic matter‐lean muds may also be black when their iron sul-
            fine‐grained sedimentary rock, then “there are no shales in the subsurface,   fide content is high (e.g., Potter et al., 2005); however, they become light‐
            only potential shales” (Weaver, 1989, p. 6). Some rocks which are referred   colored on lithification as the sulfide changes into either marcasite or pyrite
            to in the literature as shales are actually metasedimentary rocks produced by   (Twenhofel, 1939). Black shale is the general term for any dark‐colored,
            regional low‐grade metamorphism, and should therefore be called slates.  fine‐grained, organic matter‐rich sedimentary rock. In the words of Stow
            2  Mud is the name given to particles or collections of particles smaller than   et al. (1996, p. 403): “[m]any black shales are hemipelagites; others, such as
            sand, that is, smaller than 62.5 µm, that is, silt and clay, which typically   black cherts and organic matter‐rich limestones, are pelagites; whereas still
            occur together. Some authors talk about “mud and silt,” perhaps making   others are fine‐grained turbidites.” This de facto usage has also been noted
            “mud” a synonym of “clay.” Operationally, the mud/sand boundary may be   by Arthur (1979) who states that “the term ‘black shale’ is used in a general
            defined  based  on  sieve  sizes  around  this  value.  Because  mud is  a  term   sense to refer to relatively organic carbon‐rich […] mudstone and marlstone
            related to grain size, it has no connotations as to composition.  which may or may not be ‘shale’ in the classical sense.”

            Fundamentals of Gas Shale Reservoirs, First Edition. Edited by Reza Rezaee.
            © 2015 John Wiley & Sons, Inc. Published 2015 by John Wiley & Sons, Inc.
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