Page 74 - Fundamentals of Geomorphology
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GEOMORPHIC MATERIALS AND PROCESSES         57


              (a clay mineral), and silicic acid, H 4 SiO 4 :  graze them (e.g. Yatsu 1988, 285–397; Spencer 1988;
                                                        Trenhaile 1987, 64–82).This process is particularly effec-
              2HAlSi 3 O 8 + 9H 2 O → Al 2 Si 2 O 5 (OH) 4 + 2H 4 SiO 4  tive in tropical limestones. Boring organisms include
                                                        bivalve molluscs and clinoid sponges. An example is the
              The silicic acid is soluble in and removed by water  blue mussel (Mytilus edulis). Grazing organisms include
              leaving kaolinite as a residue, a process termed desili-  echinoids, chitons, and gastropods, all of which dis-
              cation as it involves the loss of silicon. If the solution  place material from the rock surface. An example is the
              equilibrium of the silicic acid changes, then silicon  West Indian top shell (Cittarium pica), a herbivorous
              dioxide (silica) may be precipitated out of the solution:  gastropod.
                                                          Under some conditions, bacteria, algae, fungi, and
              H 4 SiO 4 → 2H 2 O + SiO 2                lichens may chemically alter minerals in rocks. The
                                                        boring sponge (Cliona celata) secretes minute amounts
              Weathering of rock by hydrolysis may be complete or  of acid to bore into calcareous rocks. The rock miner-
              partial (Pedro 1979). Complete hydrolysis or alliti-  als may be removed, leading to biological rock erosion.
              zation produces gibbsite. Partial hydrolysis produces  In an arid area of southern Tunisia, weathering is con-
              either 1 : 1 clays by a process called monosiallitiza-  centrated in topographic lows (pits and pans) where
              tion, or 2 : 1 and 2 : 2 clays through a process called  moisture is concentrated and algae bore, pluck, and etch
              bisiallitization (cf. pp. 159–60).        the limestone substrate (Smith et al. 2000).
                                                          Humans have exposed bedrock in quarries, mines,
              Chelation                                 and road and rail cuts. They have disrupted soils by det-
                                                        onating explosive devices, and they have sealed the soil
              This is the removal of metal ions, and in particular  in urban areas under a layer of concrete and tarmac.
              ions of aluminium, iron, and manganese, from solids  Their agriculture practices have greatly modified soil
              by binding with such organic acids as fulvic and humic  and weathering processes in many regions.
              acid to form soluble organic matter–metal complexes.
              The chelating agents are in part the decomposition
              products of plants and in part secretions from plant
              roots. Chelation encourages chemical weathering and  SEDIMENT TRANSPORT
              the transfer of metals in the soil or rock.
                                                        A river in flood demonstrates sediment transport,
                                                        the dirty floodwaters bearing a burden of mate-
              Biological weathering
                                                        rial derived from the land surface. As well as the
              Some organisms attack rocks mechanically, or chemi-  visible sediment, the river also carries a load of material
              cally, or by a combination of mechanical and chemical  in solution. Geomorphologists often distinguish between
              processes.                                sediment transport, which is essentially mechanical, and
                Plant roots, and especially tree roots, growing in bed-  solutional transport, which is essentially chemical; they
              ding planes and joints have a biomechanical effect –as  also discriminate between processes involving a lot of
              they grow, mounting pressure may lead to rock fracture.  sediment moving en masse – mass movement – and sed-
              Dead lichen leaves a dark stain on rock surfaces.The dark  iment moving as individual grains more or less dispersed
              spots absorb more thermal radiation than the surround-  in a fluid – fluid transport (cf. Statham 1977, 1). In
              ing lighter areas, so encouraging thermal weathering.  mass movement, the weight of sediment is a key con-
              A pale crust of excrement often found below birds’ nests  trolling factor of motion, whereas in fluid transport the
              on rock walls reflects solar radiation and reduces local  action of an external fluid agency (wind or water) is
              heating, so reducing the strength of rocks. In coastal  the key factor. However, the distinction blurs in case
              environments, marine organisms bore into rocks and  of slow mass movements, which resemble flows, and in
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