Page 22 - Gas Wettability of Reservoir Rock Surfaces with Porous Media
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6       Gas Wettability of Reservoir Rock Surfaces with Porous Media





                                              Gas phase               Gas phase
                                        θ < 90º
                                   h                                                    Liquid phase
                                                         θ = 90º

                                                                          θ < 90º
                                                                                      h<0
                                                               phase
                                                                Liquid
                                         Liquid
                                        phase
                                Strong liquid-wetting  Intermediate gas-wetting  Gas-wetting
                            FIGURE 1.4
                            Capillary rise tests under different gas wettability conditions.

                            In 1997, Al-Siyabi et al. [9], measured the CA of oil on the surface of rocks in
                            four groups of gas/oil systems (C 1 /nC 4 ,C 1 /nC 8 ,C 1 /nC 10 ,and C 1 /nC 14 ) under
                            reservoir-like conditions. The results showed that when the surface tension is
                            larger than 0.2 dyn/cm, the CA of oil is about 20 degrees.
                            Li Kewen et al. [10,11], initially proposed the concept of “gas wettability” (see
                            Fig. 1.4) based on liquid wettability in 2000. They studied and proved this
                            with a simple network model. Gas wettability was realized in reservoirs near
                            well walls that could boost productivity of condensate gas reservoirs, and the
                            wettability of porous media changed into preferential gas wetting from prefer-
                            ential liquid wetting by using fluorocarbon polymers FC754 and FC722 in the
                            laboratory.
                            Therefore, in a “gas/liquid/solid” system, the liquid can’t always wet the solid
                            surface completely, compared to gas. The gas wetting ability of solids has a
                            greater difference in different systems.


                            1.2    RESEARCH STATUS OF GAS WETTABILITY IN
                            CHINA AND OVERSEAS
                            1.2.1   Research Status of Gas Wettability Overseas

                            Based on the concept, principle, and method of liquid wettability on the sur-
                            face of reservoir rocks, Li Kewen and Firoozabadi [10] initially proposed the
                            concept of “gas wettability” in 2000, and a new idea for improving gas well
                            productivity was suggested by changing the wettability of condensate gas reser-
                            voir from preferential liquid wetting into preferential gas wetting. A new direc-
                            tion for reservoir wettability study was proposed. Later, some international
                            researchers studied the application of gas wettability in enhancing oil recovery
                            and water plugging and finally got some knowledge.
                            Li Kewen et al. [10], studied the effects of gravity, viscosity, interfacial tension,
                            and wettability of condensate gas reservoir on the critical condensate satura-
                            tion and relative permeability, making use of a simple network model. The
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