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Gas geochemistry surveys for petroleum                               227

           concentrations  than  those  found  in  the  anomalies,  so  hydrocarbons  must  have  been
           added.  Both  of these  observations  can  be  explained  by  ascending  hydrocarbons  being
           trapped  during  the  formation of secondary carbonates,  and released  and  detected  by the
           acid  treatment  method  used  to  analyse  the  samples.  The  river valley,  filled  with  loose
           sediments, might follow a good conduit for ascending hydrocarbon gases.
              Still  other  factors  point  to  the  significance  of  the  anomalies.  The  hydrocarbon
           anomalies  in the  river bank sediments  include  the  complete  range  from C1  to  C5,  which
           excludes  the  possibility  of the  hydrocarbon  anomaly being  of surface  biological  origin.
           The  aeolian  sand is a comparatively poor medium  for the  development and detection  of
           hydrocarbon  anomalies  in  soil, but  is highly suitable  for the  detection  of Hg  in  soil  air,
           for which there is no obvious source other than natural gas at depth.
              Subsequently the  scientific  research  well was  drilled as planned.  When  it penetrated
           Lower  Ordovician  carbonates  it  produced  16.3  x  104  m 3 per  day  of  natural  gas.  The
           scientific research well thus became the discovery well in this region.  Since the well was
           drilled directly on the surface hydrocarbon gas anomaly, the soil gas survey traverse was
           thought to  cross  an  apical  or  linear  anomaly.  Further  work,  however,  was  to  reveal  that
           the gas field has an annular anomaly.
              Encouraged  by  the  gas  discovery,  the  Changqing  Oil  Company  decided  to  explore
           the  full  extent of the  field.  In  1990,  a 5035  km 2 area  was  covered by a gas geochemical
           survey with a target sample density of 1-2 per km 2 which yielded a total of 6162  sample
           sites.  At  each  site  C~ and  He  were  measured  in the  interstitial  soil  air,  and  soil  samples
           were  analysed  in  the  laboratory by the  acid treatment  method  for Cj-C5  and by  thermal
           desorption  at  250~  for Hg.  The  random  data  points  were  gridded  by  inverse  distance
           squared weighting, smoothed by means of a 3 x 3 moving average and contoured.
              The resulting hydrocarbon gas patterns and Hg pattems are presented in Figs.  6-8 and
           6-9,  respectively  (which  also  show  the  location  of  the  traverse  discussed  above  and
           shown in Fig. 6-7). The regional pattems comprise an arc of anomalous values extending
           from the southwest to the northeast.  This arc  is interpreted  as part of an annular anomaly
           that  is  still  open  to  the  north  and  west.  The  exploration  implication  is  that  a  gas  field
           underlies  the  low  values  in  the  northwest  of  the  survey  region.  In  fact  the  earlier  gas
           survey  traverse  and  the  scientific  research  well  that  became  the  discovery  well  were
           already located in this part of the region.
              Subsequently  the  Changqing  Oil  Company  drilled  more  than  twenty  wells,  most  of
           them  commercial,  in  the  prospective  area  (Figs.  6-8  and  6-9).  The  highest  production
           from  a  well  in  this  area  is  more  than  120  x  104  m 3 per  day.  The  gas  reserves  in  the
           Jingbian  field  are  likely to  exceed  10 ~  m 3 as  the  field  is not  yet closed  off to  the  north
           and west by surface exploration.
              The  gas production layer is a Lower Palaeozoic  karstic plateau  at a depth of 3000 m,
           surrounded by palaeo-valleys filled with a Permo-Carboniferous coal series (which could
           be  the  source  of  the  natural  gas).  The  annular  surface  geochemical  anomaly  may  be
           related  to  the  edge  of  the  buried  plateau.  In  the  production  layer,  the  gas  is  under  a
           pressure  of  120  atmospheres.  Therefore  the  average  pressure  gradient  between  the  gas
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