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Soil Minerals
                                                                                           Soil Minerals  137

                  not be allowed to air-dry and should be stored in sealed plastic bags or other
                  containers.

                  Whenever soils are air-dried prior to testing, this and the procedure used to
                  rehydrate should be stated in the test report.


                  6.5   LIME STABILIZATION OF EXPANSIVE CLAY


                  6.5.1  Overview

                  Mixing hydrated lime, Ca(OH) 2 , with soil to make it stronger dates from
                  prehistory, and lime mortar was used for masonry walls well into the twentieth
                  century. In modern times lime is mixed with clay soil and compacted for road
                  bases. A more recent adaptation of this procedure is to simply drill holes into an
                  expansive clay layer and either mix the soil with hydrated lime or fill the open
                  borings with quicklime. It therefore is important to recognize the chemical
                  reactions that take place.


                  6.5.2  Flocculation with Lime
                  An immediate reaction between expansive clay and lime will be observed as the
                  clay appears to dry up and becomes crumbly, even though there is no change in
                  the water content. The reason for this is that the clay particles become stuck
                  together, and the clay is said to be flocculated. This stabilizes the expansive nature
                  and greatly increases the clay strength. A simple method for ‘‘drying’’ expansive
                  clay in a mudhole without really drying it is to dump in a bag or two of hydrated
                  lime and mix it in.

                  This change occurs even though the clay already is calcium-saturated, so one

                  hypothesis to explain the sudden flocculation is that OH ions from dissolved
                            þ
                  lime pull H ions from within the clay crystals to make water, and in doing so
                  increase the negative charge on the clay. This is called a ‘‘pH-dependent charge.’’
                  The negative charge is balanced by the Ca 2þ  ions that remain outside of the clay
                  layers and link clay particles together.


                  6.5.3  Why Use Quicklime?
                  For safety reasons hydrated lime is preferred for mixing with soil for road bases,
                  but quicklime is preferred for filling borings in a procedure called ‘‘drilled lime.’’
                  There are several reasons for this.

                  First, the quicklime quickly extracts water from the soil, hydrates, and approx-
                  imately doubles in volume. The drying action can quickly stop a landslide, and
                  as the lime hydrates and expands, the surrounding expansive clay shrinks and

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