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Hydrate of natural gas                      133












































            FIG. 5.25  Marha well drilling rig covered with gas hydrates after a blowout. Photo by Yuri Makogon, 1963, personal
            communication, 1999.

              1963 Europe onshore
              Marha well drilling rig got covered with gas hydrates after a blowout as shown in Fig. 5.25.
            T = −57 °C. The blowout gradually sealed itself. Sample placed in water in an upside-down
            glass actively offgassed as a hydrate. As the air temperature warmed up to −40° hydrate
            converted to ice.
              According to Makogon and Omelchenko (2012), the Markha River field not the Markha
            well should be considered the first discovery of a gas hydrate field in 1963. The well reached
            a gas deposit at 1830 m depth, with reservoir temperature of no greater than 3.8 °C.
              January 1966 Europe LPG storage tank valve
              3/4 in. sampling valve in LPG storage sphere had a faulty handle. Operator used a 2 in.
            drain valve to take LPG sample rather than using 3/4 in. sampling valves. A solid plug of ice
            or hydrate stopped the flow which suddenly cleared with a large release of propane which
            ignited.
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