Page 637 - Handbook of Battery Materials

References 611

Table 17.19 (continued)

−1
2
◦
System c T ( C) Method D(cm ·s ) References
+
LiN(C 2 F 5 SO 2 ) 2 1mol·L −1 – pfg-NMR D(Li ) = [455]
in EC/EMC 1.70 × 10 −6
(2/8)
−
D(N(C 2 F 5 SO 2 ) ) =
2
1.83 × 10 −6
LiClO 4 in PC 1 mol·L −1 25 Moir´ e pattern D(LiClO 4 ) = [502]
1.2·10 −6
LiClO 4 in PC 0.1mol·L −1 25 Microelectrode/ D(LiClO 4 ) = [494]
macroelectrode 2.88 × 10 −6
+
LiPF 6 in 1mol·L −1 – pfg-NMR D(Li ) = [455]
EC/DMC (1/1) 2.20 × 10 −6
−
D(PF 6 ) =
2.94 × 10 −6
+
LiPF 6 in PC 0.5mol·L −1 25 pfg-NMR D(Li ) = [425]
0.25 × 10 −6
LiPF 6 in 1mol·L −1 RT Restricted D(LiPF 6 ) = [503]
EC/DEC (1/1) diffusion 1.48 × 10 −6
LiPF 6 in AN 1 mol·L −1 RT Restricted D(LiPF 6 ) = [503]
diffusion 2.11 × 10 −5
LiPF 6 in 1mol·L −1 25 Concentration- D(Li ) = 9.7 × 10 −8 [512]
+
EC/DEC/DMC difference per
(2/1/2) microelectrode
LiPF 6 in 1mol·L −1 21 Restricted D(LiPF 6 ) = [478]
PC/EC/DMC diffusion 3.13 × 10 −6
(1/2.7/6.3)
+
LiPF 6 in 10 w% 25 pfg-NMR D(Li ) = [499]
BMITFSI c 4.74 × 10 −8
−
D(PF 6 ) =
6.43 × 10 −8
a
LiTFSI: LiN(SO 2 CF 3 ) 2 lithium bis(trifluoromethanesulfonyl)imide.
b DEME: N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium.
c
BMITFSI: 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide.
References

1. Jasinsky, R. (1967) High-Energy Batter- 4. Herr, R. (1990) Electrochim. Acta, 35,
ies, Plenum, New York. 1257.
2. Besenhard, J.O. and Eichinger, G. 5. Blomgren, G.E. (1983) in Lithium Bat-
(1976) J. Electroanal. Chem. Interfacial
teries, Chapter 2 (ed. J.-P. Gabano),
Electrochem., 68,1.
Academic Press, London.
3. Jasinsky, R. (1970) in Advances in
6. Dominey, L.A. (1994) in Lithium Bat-
Electrochemistry and Electrochemical
Engineering, vol. 7 (eds P. Delahay teries. New Materials, Developments and
and P.C.W. Tobias), Interscience, New Perspectives, Chapter 4 (ed. G. Pistoia),
York, p. 77. Elsevier, Amsterdam.