Page 88 - Handbook of Hazardous Chemical Properties

78 CAMPHENE
Fire Hazards - Flash Point: Not flammable but can spontaneously ignite if in contact with water;
FlammableLimits in Air (9%): Not flammable; Fire Extinguishing Agents: Extinguish adjacent fires with
dry chemical or carbon dioxide; Fire Extinguishing Agents Not To Be Used Water, foam; Special
Hazards of Combustion Products: Not pertinent; Behavior in Fire: Can cause spontaneous ignition if
wetted. Generates dense smoke of phosphoric acid; Ignition Temperature: Not pertinent; Electrical
Hazard Not pertinent; Burning Rate: Not pertinent.
Chemical Reactivity - Reactivity with Water: Reacts vigorously with water, generating phosphine,
which is a poisonous and spontaneously flammable gas; Reactivity with Common Materials: Can react
with surface moisture to generate phosphine, which is toxic and spontaneously flammable; Stability
During Transport: Stable if kept dry; Neutralizing Agents for Acids and Caustics: Not pertinent;
Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

CAMPHEIVX
Chemical Designations - Synonyms: 2,2-Dimethyl-3-Methyl-enenorbornane; 3,3-Dimethyl-2-
Methylenenorcamphane; Chemical Formula: Ca,,H,,.
Observable Characteristics - Physical State (as normally shipped): Solid; Color: White; Odor:
Camphoraceous.
Physical and Chemical Properties - Physical State at 15 “c and I atm. : Solid; MolenrIar Weight:
136; Boiling Point at I atm. : 310; 154; 427; Freezing Point: 122; 50; 323; Critical Temperature: Not
pertinent; Critical Pressure: Not pertinent; Specific Gravity: 0.87 at 15°C (solid); Vapor (Gas) Density:
Not pertinent; Ratio of S’pecipc Heats of Vapor (Gas): Not pertinent; Latent Heat of Vaporization: Not
pertinent; Heat of Combustion: -19,400, -10,800, -452; Heat of Decomposition: Not pertinent.
Health Hazards Information - Recommended Personal Protective Equipment: Gloves and face shield;
Symptoms Following Exposure: Inhalation causes irritation of nose and throat. Contact with eyes and
skin causes irritation; General Treatment for Enposure: INHALATION: move to fresh air; call a
physician immediately. EYES: flush immediately with clean, cool water; SKIN: wash with alcohol,
follow with soap and water wash; Toxicity by Inhalation (ThresholdLimit Value): Data not available;
Short-Term Exposure Limits: Data not available; Toxicity by Ingestion: Data not available; Late
Toxicity: Data not available; Vapor (Gas) Irritant Characteristics: Data not available; Liquid or Solid
Irritant Characteristics: Data not available; Odor Threshold Data not available.
Fire Hazards - Flash Point (deg. F): 108 OC, 92 CC; Flammable Limits in Air (W): No data; Fire
Extinguishing Agents: Foam, dry chemical, carbon dioxide; Fire Extinguishing Agents Not To Be Used
Water; Special Hazards of Combustion Products: No data; Behavior in Fire: No data; Ignition
Temperature: No data; Electrical Hazard No data; Burning Rate: Not pertinent.
Chemical Reactivity - Reactivity with Water: No reaction; Reactivity with Common Materials: No data;
Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent;
Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

CARBOLIC OIL
Chemical Designations - Synonyms: Middle Oil; Liquefied Phenol; Chemical Formula: C,J&OH.
Observable Characteristics - Physical State (as normally shipped): Liquid; Color: Colorless, darkens
on exposure to light; Odor: Sweet, tar-like.
Physical and Chemical Properties - Physical State at 15 “c and I a. Liquid; Molecular Weight:
:
84.11; BoilingPointatI atm.: 358.2; 181.8; 455.0; Freezingpoint: < 105.6; C40.9; <314.1; Critical
Temperature: 790.0, 421.1, 694.3, Critical Pressure: 889, 60.5,6.13; Specific Gravity: 1.04 at 41°C
(liquid); Vqor (Gas) Density: Not pertinent; Ratio of Specific Heats of Vapor (Gas): 1.089; Latent
Heat of Vaporization: 129.6; 72.0; 3.014; Heat of Combustion: -13,401, -7,445, -311.707; Heat of
Decomposition: Not pertinent.
Health Hazards Information - Recommended Personal Protective Equipment: Fresh air mask for con-
fined areas; rubber gloves; protective clothing; full face shield; Symptoms Following Exposure: Will
burn eyes and skin. The analgesic action may cause loss of pain sensation. Readily absorbed through
skin, causing increased heart rate, convulsions, and death; General Treatment for Exposure: