Page 183 - Handbook of Properties of Textile and Technical Fibres

160 Handbook of Properties of Textile and Technical Fibres

(a) ⊥ (c) ⊥

64
3013
230
257

72 2936
// //

2984
3285
Raman intensity 100 253 300 3000 3300
147
3325
3064

⊥
(b)
1085 Amide III
1401
Amide I
1002
1448
1615

1665
//
β
°CC
ρ CH 3 444
1003 °CC β
1405 O 2

Figure 5.12 Peak fitting of the Raman signature of Bombyx mori degummed single fiber at 0%
strain for parallel and perpendicular polarizations. Note the narrow peaks due to neon lamp
used as very accurate internal reference wave number: (a) low wave number modes involving
1
the motion of ordered (narrow w145 cm 1 peak, see Fig. 5.5; (b) CeH(w2930e3070 cm ),
1
1
NeH (3285 cm ), and H 2 O (3325 cm ) stretching modes; and (c) Amide I and Amide III
mode region.
After Colomban P, Dinh HM, Riand J, Prinsloo LC, Mauchamp B: Nanomechanics of single
silkworm and spider fibres: a Raman and micromechanical in situ study of the conformation
change with stress, J Raman Spectrosc 39:1749e1764, 2008a and Colomban P, Moukit SE,
Dinh HM, Hassine M, Riand J, Mauchamp B: Micro- & nano-mécanique des fibres naturelles
(animales), Revue des Matériaux Compos Avancés 18:163e168, 2008b.