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                                                         Groundwater quality and contaminant hydrogeology  231


                   Table 6.6 Summary of chlorinated solvents detected in groundwater in the Birmingham Triassic sandstone aquifer. Solvent abbreviations
                   are given in Table 6.3. After Rivett et al. (1990).
                   Industrial solvents               TCE          TCA        PCE         TCM         CTET
                   % boreholes with solvent detected   78          46         44         53          37
                   Proportion of boreholes exceeding (%)
                     1 mgL −1                          62          22          9         17           2
                     10 mgL −1                         43          13          4          0           0
                     100 mgL −1                        30          5           2          0           0
                                           −1
                   Maximum concentration detected (mgL )  5500    780        460          5           1





















                   Fig. 6.19 Organic solvent contamination of the urban Birmingham Triassic sandstone aquifer showing: (a) distribution of groundwater
                   sampling points and industrialized areas; (b) distribution of maximum trichloroethene (TCE) concentrations. After Rivett et al. (1990).



                   in the Nottingham Triassic sandstone aquifer in the  6.4.2 Municipal landfill, domestic and
                   English Midlands has shown that although the inor-  cemetery wastes
                   ganic quality of the groundwater may be accept-
                   able for water supply, high nitrate concentration   The landfilling of municipal wastes is common prac-
                   and microbial contamination relating to untreated  tice, with older sites up until the late 1980s formerly
                   sewage inputs from broken or leaking sewers are  operated under a ‘dilute and disperse’ principle where
                   causes for concern (Barrett et al. 1999; Cronin et al.  leachate generated in the waste was allowed to migrate
                   2003; Powell et al. 2003; Fukada et al. 2004). Also,  away from the site and disperse in groundwater below
                   research in Berlin has shown that polar pharma-  the water table. This practice is no longer allowed
                   ceutical compounds such as clofibric acid, diclofenac,  in Europe, with engineered solutions required to
                   ibuprofen, propyphenazone, primidone and carba-  contain leachate in the landfill site. A typical solution
                                                          −1
                   mazepine are detectable at individual trace (µgL )  is to line the site with an artificial liner with a low
                                                                                                   −1
                                                                                               −9
                   levels in surface waters and groundwaters with a  design permeability of no higher than 10 ms and
                   source in municipal sewage treatment plants (Heberer  to install a leachate collection system for subsequent
                   2002). Waste discharge to surface water courses infil-  treatment and discharge of the leachate (Department
                   trating to groundwater was highlighted as a transport  of the Environment 1995). After completion of filling,
                   pathway for these soluble polar organic compounds,  the landfill site may be restored to agricultural land by
                   enabling migration over large distances in impacted  sealing the site with a low permeability clay cap that
                   aquifers.                                   prevents water infiltration into the buried waste.
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