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Industrial Wastewater Treatment, Recycling, and Reuse: An Overview  25


                                                                   Adsorption
                                                                   Biological
                                                                   Oxidation
                                            Zone-I                 Membrane
                                                                   Coagulation
                                                                   Ion exchange
                  1000
                                                                   Extraction
                                                                   Cavitation
                 No. of Publications  100   Zone-II




                    10



                     1
                      1970     1980     1990     2000     2010
                                          Year
              Figure 1.10 Trends in separation processes for wastewater treatment.

                 Zone II: Corresponds to processes such as extraction and cavitation,
              which are less commonly employed in the industrial wastewater treatment.
              For extraction, typical applications remove pollutants such as phenol and
              such acids/organics from the wastewaters. The important drawback of
              the extraction processes lies in the fact that the selection of an extractant
              is very crucial, and the major cost is in the recovery of extractant, apart from
              the cost of extractant itself. Further, loss of an extractant in the wastewater
              can pose further pollution problems. As far as the cavitation process is con-
              cerned, it is evident that up to 2000, there were a very few publications con-
              cerning wastewater treatment, and there has been a marked increase in
              interest after 2000. However, in terms of industrial applications in wastewa-
              ter treatment, there is still a very long way to go.
                 There has been huge interest in membrane separations in wastewater
              treatment with a number of modifications in the form of membranes and
              technology (Figure 1.11). MF applications outnumber several other pro-
              cesses, mainly due to the fact that these are required for removal of sus-
              pended solids and for removal of larger molecules. After MF, there has
              been a lot of attention to RO, which is again crucial in water recycling
              and reuse. In comparison, research in the area of other membranes, espe-
              cially NF, is far from being well developed.
                 Similarly, in the area of biological separations in wastewater treatment,
              there is marked interest in the area of anaerobic treatment as compared to
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