Page 390 - Instant notes

Index 376

π orbital, 186, 188, 190
π−π* transition, 261
p-orbital, 188
Paired spin, 190, 193, 262
Parity, 222
Partial pressure, 2, 3, 54, 75
Dalton’s law of, 2–3
Partial vapour pressure, 76
Partially miscible liquids, 88–89
Particle
in a box, 177–180
in a circular orbit, 180–181, 246
Particle-wave duality, 168–173
Partition coefficient, 55
Partition function, 140, 201–203
entropy, 202–203
heat capacity, 203–204
internal energy, 202
separation of, 202
thermodynamic parameters and, 202–203
Partitioning, 55
Paschen series, 184
Path Function, 29
Pauli exclusion principle, 191–192, 209, 273
Pauling electronegativity scale, 224
Penetration, 190, 195, 197
Perfect gas, 1–3, 84
equation of state, 2
equations, 2
Periodicity, 192, 194–197
pH
scale, 59
titration, 65
Phase, 87
Phase diagram
liquid-vapor, 91–94
single species, 83–85
solid-liquid, 89–90
temperature-composition, 88
two components, 87–88
Phase rule, 87
Phosphorescence, 261
Photochemical rate law, 150
Photoelectric effect, 171–172
Photoelectron spectroscopy, 263
Photon, 169, 171, 238
Photosynthesis, 265
Physical transition, 54
Planck’s constant, 169, 172
Planck’s law, 170
Polar covalent bond, 224
Polarizability, 232, 249, 258