Page 393 - Instant notes

Index 379

redox, 102
spontaneous, 52, 107
stoichiometry, 53
standard enthalpy change for cell, 108
standard entropy change for cell, 108
standard free energy change for cell, 108
standard volume change for cell, 108
termination, 153
unimolecular, 128, 142–143, 147–149
volume change for cell, 108
Redox electrode, 104
Redox reaction, 102
Redox-active ion, 104
Reduced mass, 184, 247, 252
Reducing agent, 102
Reductant, 102
Reduction, 102
Reduction potential, standard, 107–108
Reference electrode, 107
Reflections, 24–25
requirements for allowed, 24
Relative atomic mass, 161
Repulsion energy, 233–234
Resonance hybrid, 207
Reversible process, 40
Right-hand electrode, 106
Rigid rotor, 246
Root mean square (rms) speed, gas molecule, 6
Rotational
constant, 247
partition function, 203
quantum number, 247
Rotational spectroscopy, 246–250
energy levels, 246–248
intensities, 248
Raman, 249–250
selection rules, 248
transitions, 248
Rule of mutual exclusion, 258
Rydberg series, 184, 197

σ (sigma) bond, 210–211
s orbital, 186, 187, 190
Sackur-Tetrode equation, 203
Salt, 95
partially (sparingly) soluble, 70
solutions, 63
Salt bridge, 103, 106, 111
Saturated calomel electrode, 112
Saturated solution, 70
Schrödinger equation, 175, 190