Page 397 - Instant notes

Index 383

third law, 43
Third law of thermodynamics, 43
Third order, 130, 144
Tight binding approximation, 226–227
Tightly bound electron model, 226–227
Titrant, 65
Titration, 65
acid-base, 65
curves, 65–67
pH, 65
Total energy criterion, 200
Total intermolecular interaction energy, 234
Total number criterion, 200
Total orbital angular momentum quantum number, 192, 222
Total spin angular momentum quantum number, 192, 222
Transition probability, 239, 243, 260
Transition state theory, 139–141
Transition, 237, 239
charge transfer, 261
electronic, 197, 260–261
n-π*, 261
π-π*, 261, 266
rotational, 248
rotational Raman, 249–250
vibrational, 253–254
vibrational Raman, 258
Translational heat capacity (gas), 203
Translational partition function, 203
Transmittance, 244
Transmutation, 163
Transport number, 117
limiting, 117
Triclinic unit cell, 18
Trigonal unit cell, 18
Triple point, 84, 85
Triplet (NMR), 272
Triplet state, 193, 222, 262, 273
Trouton’s Rule, 42
Tunneling, 181–182
Turning point, 260
Two component phase diagram, 87–88

Ultraviolet catastrophe, 169–171
Uncertainty principle, see Heisenberg’s uncertainty principle
Ungerade, 222
Unimolecular reaction, 128, 142–143
Unit cell, 18–20
dimensions from diffraction, 25, 26
edge and angle notation, 18
rules for selecting, 19
Unpaired spin, 190, 193, 262, 273