Page 75 - Materials Chemistry, Second Edition
P. 75
L1644_C02.fm Page 52 Tuesday, October 21, 2003 3:07 PM
that constitute elements of the eco-vectors can be found in Expression 2.1 (for
instance, Boustead, 1993a, b, c and Frischknecht et al., 1996).
The product of any process mass flow M [kg/s] and its corresponding eco-vector
(v m,M ) gives the rate of pollutants (P) — expressed in kg/s or EL/s — generated by
this mass flow until the life-cycle phase of the system, and shown in Expression 2.2:
P = M v ⋅ (2.2)
m,M
In parallel, an eco-vector (v ) is defined for the energy flows. The elements of
e
(v ), in turn, are expressed in specific energy bases, e.g., kilograms of pollutant per
e
kiloJoule. The rows of (v ) have analogous elements compared to those of the mass
e
eco-vector, as presented by Expression 2.3:
(kg / kg) or (EL / kg)
Renewable Raw Material
Not Renewable Raw Material
Air Emissions
Liquid Emissions
v = (2.3)
e
Solid Waste
Energy Losses
Radiation
Noise
Other Environmental Impacts
The product of an energy flow E [kW] and its corresponding vector (v ) gives
e,M
the pollutant flow (P ) regarding an energetic flow of the system in study. The
e
equation to calculate (P ) is shown in the following expression:
e
P = E v ⋅ (2.4)
e
The use of Expressions 2.2 and 2.4 makes it possible for the environmental loads
of the mass and energy flow, both measured in the same units, to be handled together,
once the pollutant flows obtained by these treatments are expressed respectively in
terms of natural resource consumption rate and waste release rate.
In this framework, each of the system’s inputs has an associated eco-vector and
its content must be distributed to the output of the system. The balance of each of
the elements of the eco-vector must be closed. This means that total amount of
output from a process is equal to the pollutant quantity that entered with the inlets
plus the amount of pollutant generated during its operation.
To enable this balance, the output is divided into products and wastes. In order
to differentiate both classes, a convention establishes that the waste flows have eco-
© 2004 CRC Press LLC