Page 11 - Introduction to Colloid and Surface Chemistry
P. 11

2  The colloidal state

          Electrophoretic  deposition        Sewage  disposal
          Emulsion  polymerisation           Soil  conditioning
          Food  processing                   Sugar  refining
          Grinding                           Water clarification
          Heterogeneous  catalysis           Water evaporation  control
          Ion  exchange                      Water  repellency
          Lubrication                        Wetting
          Oil-well drilling

          As  can  be  seen  from  the  second  of  these  lists,  the  existence  of
        matter in the colloidal state may be a desirable  or an undesirable  state
        of  affairs,  and so it is important  to know both  how to make and how
        to destroy  colloidal  systems.
          Colloid  science  is  very  much  an  interdisciplinary  subject,  albeit
        with certain  areas of physics and physical chemistry most  prominent.
        Owing to the complexity of most  colloidal  systems,  the subject often
        cannot  be  treated  readily  with  the  exactness  that  tends  to  be
        associated  with  much of  these  major  subject  areas.  It  is probably  a
        combination  of this lack of precision  and  its interdisciplinary  nature,
        rather than lack of importance,  that has been  responsible  in the  past
        for  an  unjustifiable  tendency  to  neglect  colloid  science  during
        undergraduate  academic  training.
          Until the  last few decades colloid  science  stood more or  less on its
        own as an almost entirely descriptive  subject which did not appear to
        fit within the  general framework of physics and chemistry. The  use of
        materials of doubtful composition,  which put  considerable  strain  on
        the  questions  of  reproducibility  and  interpretation,  was  partly
        responsible  for  this  state  of  affairs.  Nowadays,  the  tendency  is  to
        work whenever possible  with well-defined systems (e.g.  monodispersed
        dispersions,  pure  surface-active  agents,  well-defined polymeric  mater-
        ial)  which  act  as  models,  both  in  their  own  right  and  for  real  life
        systems under consideration.  Despite  the  large number of variables
        which  are  often  involved,  research  of  this  nature  coupled  with
        advances  in  the  understanding  of  the  fundamental  principles  of
        physics and  chemistry has  made  it  possible  to formulate coherent,  if
        not always comprehensive, theories  relating to many of the aspects of
        colloidal  behaviour.  Since  it  is  important  that  colloid  science  be
        understood  at both descriptive and theoretical  levels, the study of this
        subject  can  range  widely from  relatively simple descriptive material
        to extremely complex theory.
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