Page 187 - Introduction to Colloid and Surface Chemistry

176 Charged interfaces

Hydrated (e.g. protein and polysaccharide) surfaces adsorb ions
less readily than hydrophobic (e.g. lipid) surfaces.

Ion dissolution

Ionic substances can acquire a surface charge by virtue of unequal
dissolution of the oppositely charged ions of which they are
composed.
Silver iodide particles in aqueous suspension are in equilibrium
with a saturated solution of which the solubility product, a Ag+ai_, is
about 10~ 16 at room temperature. With excess I~ ions, the silver
iodide particles are negatively charged; and with sufficient excess
+
Ag ions, they are positively charged. The zero point of charge is not
at pAg 8 but is displaced to pAg 5.5 (pi 10.5), because the smaller
4
and more mobile Ag " ions are held less strongly than-the I~ ions in
the silver iodide crystal lattice. The silver and iodide ions are referred
to as potential-determining ions, since their concentrations determine
the electric potential at the particle surface. Silver iodide sols have
been used extensively for testing electric double layer and colloid
stability theories.
In a similar way, hydrogen and hydroxyl ions are potential-
determining for hydrous metal oxide sols:

— M — OH + H*= — M — OH^

__M — OH + OH~= — M —O~ + H 2O

The surface electrochemistry of hydrous metal oxides is actually
much more complicated than this, with a range of individual
inorganic reactions possible, depending on factors such as surface
crystal structure.

Adsorption and orientation ofdipoles

Adsorption of dipolar molecules will not contribute to a net surface
charge, but the presence of a layer of orientated dipolar molecules at
the surface may make a significant contribution to the nature of the
electric double layer.