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                                                  APPENDIX A. DERIVATION OF TRANSPORT EQUATIONS
                               The chemical energy is positive for exothermic reactions and negative for en-
                                                            ˙
                            dothermic reactions. Evaluation of Q chem depends on the chemical reaction model
                                                                ˙
                            employed in a particular situation. The Q rad term represents the net radiation ex-
                            change between the control volume and its surroundings. Evaluation of this term, in
                            general, requires solution of integro-differential equations [48]. However, in certain
                                                                                         ˙
                            restrictive circumstances, the term may be represented analogous to Q cond with k
                            replaced by radiation conductivity k rad as
                                                               16σ T  3
                                                         k rad =      ,                       (A.31)
                                                                a + s
                            where σ is the Stefan–Boltzmann constant and a and s are absorption and scattering
                            coefficients, respectively.
                            Work Done by Surface and Body Forces
                            Following the convention that the work done on the CV is negative, it can be shown
                            that
                                          ∂                           ∂
                                    ˙
                                 −W s =      [σ 1 u 1 + τ 12 u 2 + τ 13 u 3 ] +  [τ 21 u 1 + σ 2 u 2 + τ 23 u 3 ]
                                         ∂x 1                        ∂x 2
                                            ∂
                                         +     [τ 31 u 1 + τ 32 u 2 + σ 3 u 3 ] ,             (A.32)
                                           ∂x 3

                                   ˙
                                 −W b = ρ m (B 1 u 1 + B 2 u 2 + B 3 u 3 ).                   (A.33)
                            Adding these two equations and making use of Equations A.11–A.14 can show
                            that
                                                            D    V  2
                                             ˙     ˙
                                          −(W s + W b ) = ρ m        + µ  v − p  · V,         (A.34)
                                                           Dt    2
                                    2
                            where V /2 is the mean kinetic energy and the viscous dissipation function is given
                            by

                                                   2          2         2

                                              ∂u 1       ∂u 2      ∂u 3
                                      v = 2          +         +
                                              ∂x 1       ∂x 2      ∂x 3
                                                         2                2               2

                                              ∂u 1  ∂u 2      ∂u 1   ∂u 3      ∂u 3  ∂u 2
                                         +        +       +       +        +       +        . (A.35)
                                              ∂x 2  ∂x 1      ∂x 3   ∂x 1      ∂x 2  ∂x 3
                            Combining Equations A.24–A.35 therefore leads to


                                                o
                               ∂ρ m e o  ∂(ρ m u j e )  ∂     ∂T     ∂    m  j,k  h k
                                      +            =      k m     −
                                 ∂t        ∂x j      ∂x j    ∂x j         ∂x j
                                                        D    V 2
                                                                                             ˙
                                                                                      ˙
                                                     +           − p   . V + µ  v + Q chem + Q rad .
                                                       Dt    2
                                                                                              (A.36)
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